Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

A.R. Dubrovskiy; S.A. Kuznetsov; E.V. Rebrov; J.C. Schouten

doi:10.1134/S0023158408040216

Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

A.R. Dubrovskiy, S.A. Kuznetsov, E.V. Rebrov, J.C. Schouten

Research output: Contribution to journal › Article › Academic › peer-review

8 Citations (Scopus)

Abstract

Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO4 and CO3 are catalytically more active than bulk Mo2C or the commercial catalyst Cu–ZnO–Al2O3 by one and three orders of magnitude, respectively.

Original language	English
Pages (from-to)	594-598
Journal	Kinetics and Catalysis
Volume	49
Issue number	4
DOIs	https://doi.org/10.1134/S0023158408040216
Publication status	Published - 2008

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title = "Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts",

abstract = "Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO4 and CO3 are catalytically more active than bulk Mo2C or the commercial catalyst Cu–ZnO–Al2O3 by one and three orders of magnitude, respectively.",

author = "A.R. Dubrovskiy and S.A. Kuznetsov and E.V. Rebrov and J.C. Schouten",

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T1 - Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

AU - Dubrovskiy, A.R.

AU - Kuznetsov, S.A.

AU - Rebrov, E.V.

AU - Schouten, J.C.

PY - 2008

Y1 - 2008

N2 - Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO4 and CO3 are catalytically more active than bulk Mo2C or the commercial catalyst Cu–ZnO–Al2O3 by one and three orders of magnitude, respectively.

AB - Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO4 and CO3 are catalytically more active than bulk Mo2C or the commercial catalyst Cu–ZnO–Al2O3 by one and three orders of magnitude, respectively.

U2 - 10.1134/S0023158408040216

DO - 10.1134/S0023158408040216

M3 - Article

SN - 0023-1584

VL - 49

SP - 594

EP - 598

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 4

ER -

Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

Abstract

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