Catalytic (de)hydrogenation promoted by non-precious metals-Co, Fe and Mn: recent advances in an emerging field

G.A. Filonenko, R. Van Putten, E.J.M. Hensen, E.A. Pidko

Research output: Contribution to journalReview articlepeer-review

573 Citations (Scopus)
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Abstract

Catalytic hydrogenation and dehydrogenation reactions form the core of the modern chemical industry. This vast class of reactions is found in any part of chemical synthesis starting from the milligram-scale exploratory organic chemistry to the multi-ton base chemicals production. Noble metal catalysis has long been the key driving force in enabling these transformations with carbonyl substrates and their nitrogen-containing counterparts. This review is aimed at introducing the reader to the remarkable progress made in the last three years in the development of base metal catalysts for hydrogenations and dehydrogenative transformations.

Original languageEnglish
Pages (from-to)1459-1483
Number of pages25
JournalChemical Society Reviews
Volume47
Issue number4
DOIs
Publication statusPublished - 21 Feb 2018

Funding

This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 725686). G. A. F. is sincerely thankful to J. Hutt for valuable discussions during the preparation of this manuscript. E. J. M. H. acknowledges the support from the Netherlands Center for Multiscale Catalytic Energy Conversion (MCEC). Partial support from the Government of the Russian Federation (Grant 074-U01) and the Ministry of Education and Science of the Russian Federation (Project 11.1706.2017/4.6) is acknowledged.

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