Catalytic chain transfer in a miniemulsion copolymerization of methyl methacrylate and n-butyl acrylate

S.C.J. Pierik; A.M. Herk, van; N.M.B. Smeets

doi:10.1021/ma034528a

Catalytic chain transfer in a miniemulsion copolymerization of methyl methacrylate and n-butyl acrylate

S.C.J. Pierik, A.M. Herk, van, N.M.B. Smeets

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

Abstract

This paper reports on the application of catalytic chain transfer (CCT) in miniemulsion copolymn. It has been found that Co(Et)4BF has a similar chain transfer activity in bulk as CoBF. CCT copolymns. of MMA and BA can be performed in miniemulsion; large mol. wt. redns. are achieved, and at high conversions significant macromer incorporation occurs. [on SciFinder (R)]

Original language	English
Pages (from-to)	9271-9274
Journal	Macromolecules
Volume	36
Issue number	25
DOIs	https://doi.org/10.1021/ma034528a
Publication status	Published - 2003

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title = "Catalytic chain transfer in a miniemulsion copolymerization of methyl methacrylate and n-butyl acrylate",

abstract = "This paper reports on the application of catalytic chain transfer (CCT) in miniemulsion copolymn. It has been found that Co(Et)4BF has a similar chain transfer activity in bulk as CoBF. CCT copolymns. of MMA and BA can be performed in miniemulsion; large mol. wt. redns. are achieved, and at high conversions significant macromer incorporation occurs. [on SciFinder (R)]",

author = "S.C.J. Pierik and {Herk, van}, A.M. and N.M.B. Smeets",

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T1 - Catalytic chain transfer in a miniemulsion copolymerization of methyl methacrylate and n-butyl acrylate

AU - Pierik, S.C.J.

AU - Herk, van, A.M.

AU - Smeets, N.M.B.

PY - 2003

Y1 - 2003

N2 - This paper reports on the application of catalytic chain transfer (CCT) in miniemulsion copolymn. It has been found that Co(Et)4BF has a similar chain transfer activity in bulk as CoBF. CCT copolymns. of MMA and BA can be performed in miniemulsion; large mol. wt. redns. are achieved, and at high conversions significant macromer incorporation occurs. [on SciFinder (R)]

AB - This paper reports on the application of catalytic chain transfer (CCT) in miniemulsion copolymn. It has been found that Co(Et)4BF has a similar chain transfer activity in bulk as CoBF. CCT copolymns. of MMA and BA can be performed in miniemulsion; large mol. wt. redns. are achieved, and at high conversions significant macromer incorporation occurs. [on SciFinder (R)]

U2 - 10.1021/ma034528a

DO - 10.1021/ma034528a

M3 - Article

SN - 0024-9297

VL - 36

SP - 9271

EP - 9274

JO - Macromolecules

JF - Macromolecules

IS - 25

ER -

Catalytic chain transfer in a miniemulsion copolymerization of methyl methacrylate and n-butyl acrylate

Abstract

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