C-H activation of 2,4,6-triphenylphosphinine : synthesis and characterization of the first homoleptic phosphinine-iridium(III) complex fac-[Ir(C^P)3]

L.E.E. Broeckx, W. Delaunay, C. Latouche, M. Lutz, A. Boucekkine, M. Hissler, C. Müller

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Abstract

Access to homoleptic phosphinine-based coordination compounds of d(6) metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine-iridium(III) complex, obtained by C-H activation of 2,4,6-triphenylphosphinine with [Ir(acac)(3)]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.
Original languageEnglish
Pages (from-to)10738-10740
Number of pages3
JournalInorganic Chemistry
Volume52
Issue number19
DOIs
Publication statusPublished - 2013

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