Building Reversible Nanoraspberries

E. Deniz Eren, Mohammad Amin Moradi, Heiner Friedrich, Gijsbertus de With (Corresponding author)

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

The adsorption mechanism of small positively charged silica nanoparticles (SiO2 NPs) onto larger polystyrene latex nanoparticles (PSL NPs) forming hybrid particles was studied. CryoTEM showed the morphology of these supraparticles to be raspberry-like. After surface modification of the SiO2 NPs, the optimum pH regime to initiate the formation of nanoraspberries was determined. Thereafter, their size evolution was evaluated by dynamic light scattering for different surface charge densities. Reversibility of nanoraspberry formation was shown by cycling the pH of the mixture to make interparticle forces either attractive or repulsive, while their stability was confirmed experimentally. The number of SiO2 NPs on the PSL NPs as determined with cryoTEM matched the theoretically expected maximum number. Understanding and controlling the relevant parameters, such as size and charge of the individual particles and the Debye length, will pave the way to better control of the formation of nanoraspberries and higher-order assemblies thereof.

Original languageEnglish
Pages (from-to)2232-2239
Number of pages8
JournalNano Letters
Volume21
Issue number5
DOIs
Publication statusPublished - 18 Feb 2021

Keywords

  • CryoTEM
  • Raspberry Nanoparticles
  • Self-assembly
  • Silica Nanoparticles
  • Supraparticles

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