Branched polymers by chemoenzymatic self condensing vinyl polymerization

A. Heise; J.W. Peeters; E.W. Meijer; A.R.A. Palmans; C.E. Koning

Branched polymers by chemoenzymatic self condensing vinyl polymerization

A. Heise, J.W. Peeters, E.W. Meijer, A.R.A. Palmans, C.E. Koning

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

Abstract

The combination of enzymic polymn. with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymic procedure by using 2-hydroxyethyl fN-bromoisobutyrate as a bifunctional initiator. A polymerizable end-group was introduced by subsequent in-situ enzymic acrylation with vinyl acrylate. The degree of end-group functionalization of the polycaprolactone macroinimer can be controlled by the water activity in the enzymic initiation step with the double headed initiator. The degrees of functionalization of the macroinimer with the ATRP initiator were between 83 and 97 %. In the acrylation step a functionalization of 80-90 % was achieved. Self condensing ATRP of the macroinimers was successfully conducted with and without the addn. of MMA as a comonomer as evident from the increase of mol. wt. upon ATRP.

Original language	English
Title of host publication	Abstracts of papers, 229th ACS national meeting : San Diego, CA, March 13 - 17, 2005
Place of Publication	Washington D.C.
Publisher	American Chemical Society
Pages	Poly-013
ISBN (Print)	0-8412-3955-X
Publication status	Published - 2005
Event	229th ACS National Meeting - San Diego, United States Duration: 13 Mar 2005 → 17 Mar 2005

Conference

Conference	229th ACS National Meeting
Country/Territory	United States
City	San Diego
Period	13/03/05 → 17/03/05

Cite this

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title = "Branched polymers by chemoenzymatic self condensing vinyl polymerization",

abstract = "The combination of enzymic polymn. with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymic procedure by using 2-hydroxyethyl fN-bromoisobutyrate as a bifunctional initiator. A polymerizable end-group was introduced by subsequent in-situ enzymic acrylation with vinyl acrylate. The degree of end-group functionalization of the polycaprolactone macroinimer can be controlled by the water activity in the enzymic initiation step with the double headed initiator. The degrees of functionalization of the macroinimer with the ATRP initiator were between 83 and 97 %. In the acrylation step a functionalization of 80-90 % was achieved. Self condensing ATRP of the macroinimers was successfully conducted with and without the addn. of MMA as a comonomer as evident from the increase of mol. wt. upon ATRP.",

author = "A. Heise and J.W. Peeters and E.W. Meijer and A.R.A. Palmans and C.E. Koning",

year = "2005",

language = "English",

isbn = "0-8412-3955-X",

pages = "Poly--013",

booktitle = "Abstracts of papers, 229th ACS national meeting : San Diego, CA, March 13 - 17, 2005",

publisher = "American Chemical Society",

address = "United States",

note = "229th ACS National Meeting ; Conference date: 13-03-2005 Through 17-03-2005",

}

Branched polymers by chemoenzymatic self condensing vinyl polymerization. / Heise, A.; Peeters, J.W.; Meijer, E.W. et al.
Abstracts of papers, 229th ACS national meeting : San Diego, CA, March 13 - 17, 2005. Washington D.C.: American Chemical Society, 2005. p. Poly-013.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

TY - GEN

T1 - Branched polymers by chemoenzymatic self condensing vinyl polymerization

AU - Heise, A.

AU - Peeters, J.W.

AU - Meijer, E.W.

AU - Palmans, A.R.A.

AU - Koning, C.E.

PY - 2005

Y1 - 2005

N2 - The combination of enzymic polymn. with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymic procedure by using 2-hydroxyethyl fN-bromoisobutyrate as a bifunctional initiator. A polymerizable end-group was introduced by subsequent in-situ enzymic acrylation with vinyl acrylate. The degree of end-group functionalization of the polycaprolactone macroinimer can be controlled by the water activity in the enzymic initiation step with the double headed initiator. The degrees of functionalization of the macroinimer with the ATRP initiator were between 83 and 97 %. In the acrylation step a functionalization of 80-90 % was achieved. Self condensing ATRP of the macroinimers was successfully conducted with and without the addn. of MMA as a comonomer as evident from the increase of mol. wt. upon ATRP.

AB - The combination of enzymic polymn. with ATRP for the synthesis of branched (block) copolymers was investigated. Heterotelechelic polycaprolactone macroinimer was synthesized in a one-pot enzymic procedure by using 2-hydroxyethyl fN-bromoisobutyrate as a bifunctional initiator. A polymerizable end-group was introduced by subsequent in-situ enzymic acrylation with vinyl acrylate. The degree of end-group functionalization of the polycaprolactone macroinimer can be controlled by the water activity in the enzymic initiation step with the double headed initiator. The degrees of functionalization of the macroinimer with the ATRP initiator were between 83 and 97 %. In the acrylation step a functionalization of 80-90 % was achieved. Self condensing ATRP of the macroinimers was successfully conducted with and without the addn. of MMA as a comonomer as evident from the increase of mol. wt. upon ATRP.

M3 - Conference contribution

SN - 0-8412-3955-X

SP - Poly-013

BT - Abstracts of papers, 229th ACS national meeting : San Diego, CA, March 13 - 17, 2005

PB - American Chemical Society

CY - Washington D.C.

T2 - 229th ACS National Meeting

Y2 - 13 March 2005 through 17 March 2005

ER -

Branched polymers by chemoenzymatic self condensing vinyl polymerization

Abstract

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