Block copolymer hierarchical structures from the interplay of multiple assembly pathways

Alessandro Ianiro; Meng Chi; Marco M.R.M. Hendrix; Ali Vala Koç; E. Deniz Eren; Michael Sztucki; Andrei V. Petukhov; Gijsbertus de With; A. Catarina C. Esteves; Remco Tuinier

doi:10.1039/d0py00081g

Block copolymer hierarchical structures from the interplay of multiple assembly pathways

Alessandro Ianiro (Corresponding author), Meng Chi, Marco M.R.M. Hendrix, Ali Vala Koç, E. Deniz Eren, Michael Sztucki, Andrei V. Petukhov, Gijsbertus de With, A. Catarina C. Esteves, Remco Tuinier (Corresponding author)

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Structurally complex hierarchical block copolymer assemblies can be formed in solution via the interplay of multiple assembly pathways. Crystallizable block copolymers can undergo self-assembly, crystallization or phase separation in solution. By selecting appropriate solvency conditions (solvent and temperature) it is possible to induce an interplay between these processes resulting in a complex association behavior. This leads to the formation of assemblies with up to four levels of hierarchical organization. Furthermore, varying the copolymer composition enables to tune the formation mechanism and the morphology of the aggregates.

Original language	English
Pages (from-to)	2305-2311
Number of pages	7
Journal	Polymer Chemistry
Volume	11
Issue number	13
DOIs	https://doi.org/10.1039/d0py00081g
Publication status	Published - 7 Apr 2020

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Ianiro, A., Chi, M., Hendrix, M. M. R. M., Koç, A. V., Eren, E. D., Sztucki, M., Petukhov, A. V., de With, G., Esteves, A. C. C., & Tuinier, R. (2020). Block copolymer hierarchical structures from the interplay of multiple assembly pathways. Polymer Chemistry, 11(13), 2305-2311. https://doi.org/10.1039/d0py00081g

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abstract = "Structurally complex hierarchical block copolymer assemblies can be formed in solution via the interplay of multiple assembly pathways. Crystallizable block copolymers can undergo self-assembly, crystallization or phase separation in solution. By selecting appropriate solvency conditions (solvent and temperature) it is possible to induce an interplay between these processes resulting in a complex association behavior. This leads to the formation of assemblies with up to four levels of hierarchical organization. Furthermore, varying the copolymer composition enables to tune the formation mechanism and the morphology of the aggregates.",

author = "Alessandro Ianiro and Meng Chi and Hendrix, {Marco M.R.M.} and Ko{\c c}, {Ali Vala} and Eren, {E. Deniz} and Michael Sztucki and Petukhov, {Andrei V.} and {de With}, Gijsbertus and Esteves, {A. Catarina C.} and Remco Tuinier",

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Block copolymer hierarchical structures from the interplay of multiple assembly pathways. / Ianiro, Alessandro (Corresponding author); Chi, Meng; Hendrix, Marco M.R.M.; Koç, Ali Vala; Eren, E. Deniz; Sztucki, Michael; Petukhov, Andrei V.; de With, Gijsbertus ; Esteves, A. Catarina C.; Tuinier, Remco (Corresponding author).

In: Polymer Chemistry, Vol. 11, No. 13, 07.04.2020, p. 2305-2311.

Research output: Contribution to journal › Article › Academic › peer-review

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AU - Sztucki, Michael

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AU - Tuinier, Remco

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