Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films

A.J. Huckaba; A. Senes; S. Aghazada; A. Babaei; S.C.J. Meskers; I. Zimmermann; P. Schouwink; N. Gasilova; R.A.J. Janssen; H.J. Bolink; M.K. Nazeeruddin

doi:10.1021/acsomega.8b00137

Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films

A.J. Huckaba, A. Senes, S. Aghazada, A. Babaei, S.C.J. Meskers, I. Zimmermann, P. Schouwink, N. Gasilova, R.A.J. Janssen, H.J. Bolink, M.K. Nazeeruddin

Molecular Materials and Nanosystems

Research output: Contribution to journal › Article › Academic › peer-review

1 Citation (Scopus)

51 Downloads (Pure)

Abstract

The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)₃.

Original language	English
Pages (from-to)	2673-2682
Number of pages	10
Journal	ACS Omega
Volume	3
Issue number	3
DOIs	https://doi.org/10.1021/acsomega.8b00137
Publication status	Published - 2018

Fingerprint

Iridium

Cyclic voltammetry

Nuclear magnetic resonance

Thin films

picolinic acid

Cite this

Huckaba, A. J., Senes, A., Aghazada, S., Babaei, A., Meskers, S. C. J., Zimmermann, I., ... Nazeeruddin, M. K. (2018). Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films. ACS Omega, 3(3), 2673-2682. https://doi.org/10.1021/acsomega.8b00137

Huckaba, A.J. ; Senes, A. ; Aghazada, S. ; Babaei, A. ; Meskers, S.C.J. ; Zimmermann, I. ; Schouwink, P. ; Gasilova, N. ; Janssen, R.A.J. ; Bolink, H.J. ; Nazeeruddin, M.K. / Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films. In: ACS Omega. 2018 ; Vol. 3, No. 3. pp. 2673-2682.

@article{177bfc8afcf74b7189d2cba0d4374ec6,

title = "Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films",

abstract = "The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.",

author = "A.J. Huckaba and A. Senes and S. Aghazada and A. Babaei and S.C.J. Meskers and I. Zimmermann and P. Schouwink and N. Gasilova and R.A.J. Janssen and H.J. Bolink and M.K. Nazeeruddin",

year = "2018",

doi = "10.1021/acsomega.8b00137",

language = "English",

volume = "3",

pages = "2673--2682",

journal = "ACS Omega",

issn = "2470-1343",

publisher = "American Chemical Society",

number = "3",

}

Huckaba, AJ, Senes, A, Aghazada, S, Babaei, A, Meskers, SCJ, Zimmermann, I, Schouwink, P, Gasilova, N, Janssen, RAJ, Bolink, HJ & Nazeeruddin, MK 2018, 'Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films', ACS Omega, vol. 3, no. 3, pp. 2673-2682. https://doi.org/10.1021/acsomega.8b00137

Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films. / Huckaba, A.J.; Senes, A.; Aghazada, S.; Babaei, A.; Meskers, S.C.J.; Zimmermann, I.; Schouwink, P.; Gasilova, N.; Janssen, R.A.J.; Bolink, H.J.; Nazeeruddin, M.K.

In: ACS Omega, Vol. 3, No. 3, 2018, p. 2673-2682.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Bis(arylimidazole) iridium picolinate emitters and preferential dipole orientation in films

AU - Huckaba, A.J.

AU - Senes, A.

AU - Aghazada, S.

AU - Babaei, A.

AU - Meskers, S.C.J.

AU - Zimmermann, I.

AU - Schouwink, P.

AU - Gasilova, N.

AU - Janssen, R.A.J.

AU - Bolink, H.J.

AU - Nazeeruddin, M.K.

PY - 2018

Y1 - 2018

N2 - The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.

AB - The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.

UR - http://www.scopus.com/inward/record.url?scp=85043340806&partnerID=8YFLogxK

U2 - 10.1021/acsomega.8b00137

DO - 10.1021/acsomega.8b00137

M3 - Article

C2 - 29623303

AN - SCOPUS:85043340806

VL - 3

SP - 2673

EP - 2682

JO - ACS Omega

JF - ACS Omega

SN - 2470-1343