Binary and ternary transition-metal phosphides as HDN catalysts

C. Stinner, R. Prins, T. Weber

    Research output: Contribution to journalArticleAcademicpeer-review

    210 Citations (Scopus)
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    Abstract

    Transition-metal phosphides (Co2P, Ni2P, MoP, WP, CoMoP, NiMoP) were prepared by reducing metal oxide/phosphate precursors in a flow of H2. The solids obtained were tested in the hydrodenitrogenation of o-propylaniline at 643 K and 3 MPa. All the catalysts were active, with product selectivities resembling those of sulfidic catalysts. The influence of H2S on the activity and selectivities was tested and is discussed with regard to a possible surface modification. Based on the surface area of each catalyst, we estimated the relative intrinsic activities of the different phosphides. According to this estimation, MoP was intrinsically the most active catalyst.
    Original languageEnglish
    Pages (from-to)187-194
    JournalJournal of Catalysis
    Volume202
    Issue number1
    DOIs
    Publication statusPublished - 2001

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