BASF NanoSelect (TM) technology : innovative supported Pd- and Pt-based catalysts for selective hydrogenation reactions

P.T. Witte; P.H. Berben; S. Boland; E.H. Boymans; D. Vogt; J.W. Geus; J.G. Donkervoort

doi:10.1007/s11244-012-9818-y

BASF NanoSelect (TM) technology : innovative supported Pd- and Pt-based catalysts for selective hydrogenation reactions

P.T. Witte, P.H. Berben, S. Boland, E.H. Boymans, D. Vogt, J.W. Geus, J.G. Donkervoort

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Abstract

An innovative BASF catalyst manufacturing technology (NanoSelect (TM)) is introduced which allows production of heterogeneous catalysts with excellent control over metal crystallite sizes. NanoSelect (TM) technology enabled the development of Pd catalysts which are lead-free Lindlar catalyst replacements in alkyne-to-cis-alkene hydrogenations. NanoSelect (TM) Pt catalysts showed excellent chemoselectivity in substituted nitro-arene hydrogenation reactions without build-up of hydroxylamine intermediates. All NanoSelect (TM) produced catalysts show markedly higher activity per gram of metal leading to ten-fold less use of precious metal

Original language	English
Pages (from-to)	505-511
Number of pages	7
Journal	Topics in Catalysis
Volume	55
Issue number	7-10
DOIs	https://doi.org/10.1007/s11244-012-9818-y
Publication status	Published - 2012

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title = "BASF NanoSelect (TM) technology : innovative supported Pd- and Pt-based catalysts for selective hydrogenation reactions",

abstract = "An innovative BASF catalyst manufacturing technology (NanoSelect (TM)) is introduced which allows production of heterogeneous catalysts with excellent control over metal crystallite sizes. NanoSelect (TM) technology enabled the development of Pd catalysts which are lead-free Lindlar catalyst replacements in alkyne-to-cis-alkene hydrogenations. NanoSelect (TM) Pt catalysts showed excellent chemoselectivity in substituted nitro-arene hydrogenation reactions without build-up of hydroxylamine intermediates. All NanoSelect (TM) produced catalysts show markedly higher activity per gram of metal leading to ten-fold less use of precious metal",

author = "P.T. Witte and P.H. Berben and S. Boland and E.H. Boymans and D. Vogt and J.W. Geus and J.G. Donkervoort",

year = "2012",

doi = "10.1007/s11244-012-9818-y",

language = "English",

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T1 - BASF NanoSelect (TM) technology : innovative supported Pd- and Pt-based catalysts for selective hydrogenation reactions

AU - Witte, P.T.

AU - Berben, P.H.

AU - Boland, S.

AU - Boymans, E.H.

AU - Vogt, D.

AU - Geus, J.W.

AU - Donkervoort, J.G.

PY - 2012

Y1 - 2012

N2 - An innovative BASF catalyst manufacturing technology (NanoSelect (TM)) is introduced which allows production of heterogeneous catalysts with excellent control over metal crystallite sizes. NanoSelect (TM) technology enabled the development of Pd catalysts which are lead-free Lindlar catalyst replacements in alkyne-to-cis-alkene hydrogenations. NanoSelect (TM) Pt catalysts showed excellent chemoselectivity in substituted nitro-arene hydrogenation reactions without build-up of hydroxylamine intermediates. All NanoSelect (TM) produced catalysts show markedly higher activity per gram of metal leading to ten-fold less use of precious metal

AB - An innovative BASF catalyst manufacturing technology (NanoSelect (TM)) is introduced which allows production of heterogeneous catalysts with excellent control over metal crystallite sizes. NanoSelect (TM) technology enabled the development of Pd catalysts which are lead-free Lindlar catalyst replacements in alkyne-to-cis-alkene hydrogenations. NanoSelect (TM) Pt catalysts showed excellent chemoselectivity in substituted nitro-arene hydrogenation reactions without build-up of hydroxylamine intermediates. All NanoSelect (TM) produced catalysts show markedly higher activity per gram of metal leading to ten-fold less use of precious metal

U2 - 10.1007/s11244-012-9818-y

DO - 10.1007/s11244-012-9818-y

M3 - Article

VL - 55

SP - 505

EP - 511

JO - Topics in Catalysis

JF - Topics in Catalysis

SN - 1022-5528

IS - 7-10

ER -