Band-bap engineering of donor-acceptor substituted pi-conjugated polymers

H.A.M. Mullekom, van, E.W. Meijer, J.A.J.M. Vekemans

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Abstract

Some practical guidelines for the design of novel low-band-gap systems. Various donor–acceptor π-conjugated oligomers with different chain lengths containing electron-donating thiophene or pyrrole rings and electron-withdrawing 2,1,3-benzothiadiazole (like the one shown here) or quinoxaline rings have been synthesized by Stille cross-coupling. The UV/Vis absorption behavior of these systems is used to give guidelines for donor–acceptor based low-band-gap or even intrinsically conducting polymers.
Original languageEnglish
Pages (from-to)1235-1243
Number of pages9
JournalChemistry : A European Journal
Volume4
Issue number7
DOIs
Publication statusPublished - 1998

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