Atropisomeric phosphinines : design and synthesis

C. Müller, E.A. Pidko, D.I. Totev, M. Lutz, A.L. Spek, R.A. Santen, van, D. Vogt

Research output: Contribution to journalArticleAcademicpeer-review

25 Citations (Scopus)

Abstract

The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.
Original languageEnglish
Pages (from-to)5372-5375
JournalDalton Transactions
Issue number46
DOIs
Publication statusPublished - 2007

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