Atom transfer radical polymerization of 3-ethyl-3-(acryloyloxy)methyloxetane

N.K. Singha; B. Ruiter, de; U.S. Schubert

doi:10.1021/ma0401119

Atom transfer radical polymerization of 3-ethyl-3-(acryloyloxy)methyloxetane

N.K. Singha, B. Ruiter, de, U.S. Schubert

Chemical Engineering and Chemistry

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Abstract

Ethyl-3-(acryloyloxy)methyloxetane (EAO), a monomer bearing an oxetane group in the side chain, was polymerized via ATRP using ethyl 2-bromoisobutyrate (EBIB) as initiator and CuBr as a catalyst complexed with 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) as ligand. The polymer was characterized by 1H NMR, FT-IR, GPC, and MALDI-TOF-MS. 1H NMR and FT-IR analyses revealed no ring opening of the oxetane group during polymerization

Original language	English
Pages (from-to)	3596-3600
Journal	Macromolecules
Volume	38
Issue number	9
DOIs	https://doi.org/10.1021/ma0401119
Publication status	Published - 2005

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title = "Atom transfer radical polymerization of 3-ethyl-3-(acryloyloxy)methyloxetane",

abstract = "Ethyl-3-(acryloyloxy)methyloxetane (EAO), a monomer bearing an oxetane group in the side chain, was polymerized via ATRP using ethyl 2-bromoisobutyrate (EBIB) as initiator and CuBr as a catalyst complexed with 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) as ligand. The polymer was characterized by 1H NMR, FT-IR, GPC, and MALDI-TOF-MS. 1H NMR and FT-IR analyses revealed no ring opening of the oxetane group during polymerization",

author = "N.K. Singha and {Ruiter, de}, B. and U.S. Schubert",

year = "2005",

doi = "10.1021/ma0401119",

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journal = "Macromolecules",

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T1 - Atom transfer radical polymerization of 3-ethyl-3-(acryloyloxy)methyloxetane

AU - Singha, N.K.

AU - Ruiter, de, B.

AU - Schubert, U.S.

PY - 2005

Y1 - 2005

N2 - Ethyl-3-(acryloyloxy)methyloxetane (EAO), a monomer bearing an oxetane group in the side chain, was polymerized via ATRP using ethyl 2-bromoisobutyrate (EBIB) as initiator and CuBr as a catalyst complexed with 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) as ligand. The polymer was characterized by 1H NMR, FT-IR, GPC, and MALDI-TOF-MS. 1H NMR and FT-IR analyses revealed no ring opening of the oxetane group during polymerization

AB - Ethyl-3-(acryloyloxy)methyloxetane (EAO), a monomer bearing an oxetane group in the side chain, was polymerized via ATRP using ethyl 2-bromoisobutyrate (EBIB) as initiator and CuBr as a catalyst complexed with 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) as ligand. The polymer was characterized by 1H NMR, FT-IR, GPC, and MALDI-TOF-MS. 1H NMR and FT-IR analyses revealed no ring opening of the oxetane group during polymerization

U2 - 10.1021/ma0401119

DO - 10.1021/ma0401119

M3 - Article

SN - 0024-9297

VL - 38

SP - 3596

EP - 3600

JO - Macromolecules

JF - Macromolecules

IS - 9

ER -

Atom transfer radical polymerization of 3-ethyl-3-(acryloyloxy)methyloxetane

Abstract

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