Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

K. Kunna; C. Müller; J. Loos; D. Vogt

doi:10.1002/anie.200602386

Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

K. Kunna
, C. Müller
, J. Loos
, D. Vogt

Materials and Interface Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

57 Citations (Scopus)

Abstract

An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.

Original language	English
Pages (from-to)	7289-7292
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	43
DOIs	https://doi.org/10.1002/anie.200602386
Publication status	Published - 2006

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10.1002/anie.200602386

Center for Multiscale Electron Microscopy (CMEM)
Friedrich, H. (Manager), Bransen, M. (Education/research officer), Schmit, P. (Education/research officer), Schreur - Piet, I. (Other) & Spoelstra, A. (Education/research officer)
Physical Chemistry
Facility/equipment: Research lab

Cite this

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title = "Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents",

abstract = "An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.",

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AB - An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.

U2 - 10.1002/anie.200602386

DO - 10.1002/anie.200602386

M3 - Article

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Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

Abstract

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