Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

K. Kunna; C. Müller; J. Loos; D. Vogt

doi:10.1002/anie.200602386

Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

K. Kunna, C. Müller, J. Loos, D. Vogt

Materials and Interface Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

53 Citations (Scopus)

Abstract

An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.

Original language	English
Pages (from-to)	7289-7292
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	43
DOIs	https://doi.org/10.1002/anie.200602386
Publication status	Published - 2006

Access to Document

10.1002/anie.200602386

Center for Multiscale Electron Microscopy (CMEM)
Heiner Friedrich (Manager), Rick Joosten (Education/research officer), Pauline Schmit (Education/research officer), Ingeborg Schreur - Piet (Other) & Anne Spoelstra (Education/research officer)
Physical Chemistry
Facility/equipment: Research lab

Cite this

@article{9e63df77a66e49f297801024eb4020a0,

title = "Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents",

abstract = "An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.",

author = "K. Kunna and C. M{\"u}ller and J. Loos and D. Vogt",

year = "2006",

doi = "10.1002/anie.200602386",

language = "English",

volume = "45",

pages = "7289--7292",

journal = "Angewandte Chemie - International Edition",

issn = "0570-0833",

publisher = "Wiley",

number = "43",

}

TY - JOUR

T1 - Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

AU - Kunna, K.

AU - Müller, C.

AU - Loos, J.

AU - Vogt, D.

PY - 2006

Y1 - 2006

N2 - An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.

AB - An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.

U2 - 10.1002/anie.200602386

DO - 10.1002/anie.200602386

M3 - Article

VL - 45

SP - 7289

EP - 7292

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 0570-0833

IS - 43

ER -

Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents

Abstract

Access to Document

Fingerprint

Equipment

Center for Multiscale Electron Microscopy (CMEM)

Cite this