Abstract
An elegant method for the aqueous-phase hydroformylation of 1-octene with a water-soluble Rh catalyst and amphiphilic latex particles as phase-transfer agents has been developed (see scheme). In this way, substantial concentrations of the olefin in the aqueous catalyst-containing phase were reached, and thus reasonable turnover frequencies under mild reaction conditions could be achieved.
Original language | English |
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Pages (from-to) | 7289-7292 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 45 |
Issue number | 43 |
DOIs | |
Publication status | Published - 2006 |
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Dive into the research topics of 'Aqueous-phase hydroformylation of 1-octene: styrene latices as phase-transfer agents'. Together they form a unique fingerprint.Equipment
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Center for Multiscale Electron Microscopy (CMEM)
Heiner Friedrich (Manager), Rick Joosten (Education/research officer), Pauline Schmit (Education/research officer), Ingeborg Schreur - Piet (Other) & Anne Spoelstra (Education/research officer)
Physical ChemistryFacility/equipment: Research lab