Application of VAPO-5 in liquid phase oxidation reactions: Indications for the presence of different vanadiumsites

M.J. Haanepen, J.H.C. Hooff, van

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Abstract

VAPO-5's with different vanadium content (0.18 – 2.0 at%) have been used as catalyst for the liquid phase epoxidation of cinnamylalcohol (3-phenyl-2-propan-1-ol) by t-butylhydroperoxide (TBHP). It has been found that the activity, expressed as turn-over frequency (TOF), increases with increasing vanadium content. Diffuse Reflectance UV VlS (DRUWIS) shows that in samples with a high vanadium content a second type of vanadium species is present that probably is responsible for the observed higher catalytic activity.
Original languageEnglish
Title of host publicationZeolite Science 1994: Recent Progress and Discussions - Supplementary Materials to the 10th International Zeolite Conference, Garmish-Partenkirchen, Germany
EditorsH.G. Karge, J. Weitkamp
Place of PublicationAmsterdam
PublisherElsevier
Pages155-156
ISBN (Print)0-444-82308-5
DOIs
Publication statusPublished - 1995
Eventconference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22 -
Duration: 17 Jul 199422 Jul 1994

Publication series

NameStudies in Surface Science and Catalysis
Volume98
ISSN (Print)0167-2991

Conference

Conferenceconference; IZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22; 1994-07-17; 1994-07-22
Period17/07/9422/07/94
OtherIZC: International Zeolite Conference ; 10 (Garmisch-Partenkirchen) : 1994.07.17-22

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Haanepen, M. J., & Hooff, van, J. H. C. (1995). Application of VAPO-5 in liquid phase oxidation reactions: Indications for the presence of different vanadiumsites. In H. G. Karge, & J. Weitkamp (Eds.), Zeolite Science 1994: Recent Progress and Discussions - Supplementary Materials to the 10th International Zeolite Conference, Garmish-Partenkirchen, Germany (pp. 155-156). (Studies in Surface Science and Catalysis; Vol. 98). Amsterdam: Elsevier. https://doi.org/10.1016/S0167-2991(06)81131-6