Application of solvent-directed assembly of block copolymers to the synthesis of nanostructured materials with low dielectric constants

T.M. Hermans, J. Choi, B.G.G. Lohmeijer, G. Dubois, R.C. Pratt, H.-C. Kim, R.M. Waymouth, J.L. Hedrick

    Research output: Contribution to journalArticleAcademicpeer-review

    24 Citations (Scopus)

    Abstract

    An inverse relationship: Mixtures of poly(dimethylacrylamide)-block-polylactide copolymer (PDMA-b-PLA) with organosilicate oligomers (PMSSQ) selectively sequestered into the PDMA phase form micelles and inverse micelles in solution depending on the solvent. The micellar structures are imprinted into the resulting cured organosilicate to give monoliths or assemblies of densely packed organosilicate nanoparticles, respectively.
    Original languageEnglish
    Pages (from-to)6648-6652
    Number of pages5
    JournalAngewandte Chemie - International Edition
    Volume45
    Issue number40
    DOIs
    Publication statusPublished - 2006

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