Application of solvent-directed assembly of block copolymers to the synthesis of nanostructured materials with low dielectric constants

T.M. Hermans; J. Choi; B.G.G. Lohmeijer; G. Dubois; R.C. Pratt; H.-C. Kim; R.M. Waymouth; J.L. Hedrick

doi:10.1002/anie.200601888

Application of solvent-directed assembly of block copolymers to the synthesis of nanostructured materials with low dielectric constants

T.M. Hermans, J. Choi, B.G.G. Lohmeijer, G. Dubois, R.C. Pratt, H.-C. Kim, R.M. Waymouth, J.L. Hedrick

Macro-Organic Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

27 Citations (Scopus)

Abstract

An inverse relationship: Mixtures of poly(dimethylacrylamide)-block-polylactide copolymer (PDMA-b-PLA) with organosilicate oligomers (PMSSQ) selectively sequestered into the PDMA phase form micelles and inverse micelles in solution depending on the solvent. The micellar structures are imprinted into the resulting cured organosilicate to give monoliths or assemblies of densely packed organosilicate nanoparticles, respectively.

Original language	English
Pages (from-to)	6648-6652
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	40
DOIs	https://doi.org/10.1002/anie.200601888
Publication status	Published - 2006

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10.1002/anie.200601888

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abstract = "An inverse relationship: Mixtures of poly(dimethylacrylamide)-block-polylactide copolymer (PDMA-b-PLA) with organosilicate oligomers (PMSSQ) selectively sequestered into the PDMA phase form micelles and inverse micelles in solution depending on the solvent. The micellar structures are imprinted into the resulting cured organosilicate to give monoliths or assemblies of densely packed organosilicate nanoparticles, respectively.",

author = "T.M. Hermans and J. Choi and B.G.G. Lohmeijer and G. Dubois and R.C. Pratt and H.-C. Kim and R.M. Waymouth and J.L. Hedrick",

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T1 - Application of solvent-directed assembly of block copolymers to the synthesis of nanostructured materials with low dielectric constants

AU - Hermans, T.M.

AU - Choi, J.

AU - Lohmeijer, B.G.G.

AU - Dubois, G.

AU - Pratt, R.C.

AU - Kim, H.-C.

AU - Waymouth, R.M.

AU - Hedrick, J.L.

PY - 2006

Y1 - 2006

N2 - An inverse relationship: Mixtures of poly(dimethylacrylamide)-block-polylactide copolymer (PDMA-b-PLA) with organosilicate oligomers (PMSSQ) selectively sequestered into the PDMA phase form micelles and inverse micelles in solution depending on the solvent. The micellar structures are imprinted into the resulting cured organosilicate to give monoliths or assemblies of densely packed organosilicate nanoparticles, respectively.

AB - An inverse relationship: Mixtures of poly(dimethylacrylamide)-block-polylactide copolymer (PDMA-b-PLA) with organosilicate oligomers (PMSSQ) selectively sequestered into the PDMA phase form micelles and inverse micelles in solution depending on the solvent. The micellar structures are imprinted into the resulting cured organosilicate to give monoliths or assemblies of densely packed organosilicate nanoparticles, respectively.

U2 - 10.1002/anie.200601888

DO - 10.1002/anie.200601888

M3 - Article

SN - 0570-0833

VL - 45

SP - 6648

EP - 6652

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 40

ER -

Application of solvent-directed assembly of block copolymers to the synthesis of nanostructured materials with low dielectric constants

Abstract

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