Application of FTIR microscopy in combinatorial experimentation on polymer blends

R.M.A. L'Abee; W. Li; J.G.P. Goossens; M. Duin, van

doi:10.1002/masy.200850532

Application of FTIR microscopy in combinatorial experimentation on polymer blends

R.M.A. L'Abee
, W. Li
, J.G.P. Goossens
, M. Duin, van

Research output: Contribution to journal › Article › Academic › peer-review

18 Citations (Scopus)

4 Downloads (Pure)

Abstract

A novel combinatorial, high-throughput experimentation (HTE) setup has been developed, which allows for rapid mapping of the phase behavior of blends of homopolymers and block copolymers. The principle is based on the preparation of composition (ƒÖƒw-temperature (T) gradient films. Linear ƒÖ gradients were obtained over a large composition range, as shown by FTIR microscopy. The applicability of this combinatorial approach was demonstrated by studying the phase behavior of a poly(styrene-co-acrylonitrile) (SAN)/poly(methyl methacrylate-co-ethyl acrylate) (PMMA-EA) blend with varying EA content and a poly(styrene-b-butadiene-b-methyl methacrylate) (SBM) triblock copolymer.

Original language	English
Pages (from-to)	281-289
Journal	Macromolecular Symposia
Volume	265
Issue number	1
DOIs	https://doi.org/10.1002/masy.200850532
Publication status	Published - 2008

Access to Document

10.1002/masy.200850532

Cite this

@article{50372cef5f1940b5b3a968cc487db4d3,

title = "Application of FTIR microscopy in combinatorial experimentation on polymer blends",

abstract = "A novel combinatorial, high-throughput experimentation (HTE) setup has been developed, which allows for rapid mapping of the phase behavior of blends of homopolymers and block copolymers. The principle is based on the preparation of composition (ƒ{\"O}ƒw-temperature (T) gradient films. Linear ƒ{\"O} gradients were obtained over a large composition range, as shown by FTIR microscopy. The applicability of this combinatorial approach was demonstrated by studying the phase behavior of a poly(styrene-co-acrylonitrile) (SAN)/poly(methyl methacrylate-co-ethyl acrylate) (PMMA-EA) blend with varying EA content and a poly(styrene-b-butadiene-b-methyl methacrylate) (SBM) triblock copolymer.",

author = "R.M.A. L'Abee and W. Li and J.G.P. Goossens and \{Duin, van\}, M.",

year = "2008",

doi = "10.1002/masy.200850532",

language = "English",

volume = "265",

pages = "281--289",

journal = "Macromolecular Symposia",

issn = "1022-1360",

publisher = "Wiley-VCH Verlag",

number = "1",

}

TY - JOUR

T1 - Application of FTIR microscopy in combinatorial experimentation on polymer blends

AU - L'Abee, R.M.A.

AU - Li, W.

AU - Goossens, J.G.P.

AU - Duin, van, M.

PY - 2008

Y1 - 2008

N2 - A novel combinatorial, high-throughput experimentation (HTE) setup has been developed, which allows for rapid mapping of the phase behavior of blends of homopolymers and block copolymers. The principle is based on the preparation of composition (ƒÖƒw-temperature (T) gradient films. Linear ƒÖ gradients were obtained over a large composition range, as shown by FTIR microscopy. The applicability of this combinatorial approach was demonstrated by studying the phase behavior of a poly(styrene-co-acrylonitrile) (SAN)/poly(methyl methacrylate-co-ethyl acrylate) (PMMA-EA) blend with varying EA content and a poly(styrene-b-butadiene-b-methyl methacrylate) (SBM) triblock copolymer.

AB - A novel combinatorial, high-throughput experimentation (HTE) setup has been developed, which allows for rapid mapping of the phase behavior of blends of homopolymers and block copolymers. The principle is based on the preparation of composition (ƒÖƒw-temperature (T) gradient films. Linear ƒÖ gradients were obtained over a large composition range, as shown by FTIR microscopy. The applicability of this combinatorial approach was demonstrated by studying the phase behavior of a poly(styrene-co-acrylonitrile) (SAN)/poly(methyl methacrylate-co-ethyl acrylate) (PMMA-EA) blend with varying EA content and a poly(styrene-b-butadiene-b-methyl methacrylate) (SBM) triblock copolymer.

U2 - 10.1002/masy.200850532

DO - 10.1002/masy.200850532

M3 - Article

SN - 1022-1360

VL - 265

SP - 281

EP - 289

JO - Macromolecular Symposia

JF - Macromolecular Symposia

IS - 1

ER -

Application of FTIR microscopy in combinatorial experimentation on polymer blends

Abstract

Access to Document

Fingerprint

Cite this