Anomalous Glide Plane in Platinum Nano- and Microcrystals

Marie Ingrid Richard; Stéphane Labat; Maxime Dupraz; Jérôme Carnis; Lu Gao; Michaël Texier; Ni Li; Longfei Wu; Jan P. Hofmann; Mor Levi; Steven J. Leake; Sergey Lazarev; Michael Sprung; Emiel J.M. Hensen; Eugen Rabkin; Olivier Thomas

doi:10.1021/acsnano.3c01306

Anomalous Glide Plane in Platinum Nano- and Microcrystals

Marie Ingrid Richard (Corresponding author), Stéphane Labat, Maxime Dupraz, Jérôme Carnis, Lu Gao, Michaël Texier, Ni Li, Longfei Wu, Jan P. Hofmann, Mor Levi, Steven J. Leake, Sergey Lazarev, Michael Sprung, Emiel J.M. Hensen, Eugen Rabkin, Olivier Thomas

Inorganic Materials & Catalysis

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

At the nanoscale, the properties of materials depend critically on the presence of crystal defects. However, imaging and characterizing the structure of defects in three dimensions inside a crystal remain a challenge. Here, by using Bragg coherent diffraction imaging, we observe an unexpected anomalous {110} glide plane in two Pt submicrometer crystals grown by very different processes and having very different morphologies. The structure of the defects (type, associated glide plane, and lattice displacement) is imaged in these faceted Pt crystals. Using this noninvasive technique, both plasticity and unusual defect behavior can be probed at the nanoscale.

Original language	English
Pages (from-to)	6113-6120
Number of pages	8
Journal	ACS Nano
Volume	17
Issue number	6
DOIs	https://doi.org/10.1021/acsnano.3c01306
Publication status	Published - 28 Mar 2023

Bibliographical note

Funding Information:
The authors are grateful to ESRF (proposal HC4760) and PETRA (proposal 20180962EC) synchrotrons for allocating beamtime. The measurement was performed at the ID01 beamline of the European synchrotron (ESRF) and at the P10 beamline of the PETRA III synchrotron at DESY, a member of the Helmholtz Association (HGF). We thank the ID01 and P10 beamline staff for excellent support during the experiment. This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 818823) and from the DINACS ANR project (ANR-21-CE08-0033-01). The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. We also wish to thank the support by a grant from the Ministry of Science and Technology, Israel and from the Centre National de la Recherche Scientifique (CNRS), France.

Publisher Copyright:
© 2023 American Chemical Society.

Funding

The authors are grateful to ESRF (proposal HC4760) and PETRA (proposal 20180962EC) synchrotrons for allocating beamtime. The measurement was performed at the ID01 beamline of the European synchrotron (ESRF) and at the P10 beamline of the PETRA III synchrotron at DESY, a member of the Helmholtz Association (HGF). We thank the ID01 and P10 beamline staff for excellent support during the experiment. This project has received funding from the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 818823) and from the DINACS ANR project (ANR-21-CE08-0033-01). The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. We also wish to thank the support by a grant from the Ministry of Science and Technology, Israel and from the Centre National de la Recherche Scientifique (CNRS), France.

Keywords

Bragg coherent diffraction imaging
defects
dislocations
glide planes
platinum

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Cite this

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title = "Anomalous Glide Plane in Platinum Nano- and Microcrystals",

abstract = "At the nanoscale, the properties of materials depend critically on the presence of crystal defects. However, imaging and characterizing the structure of defects in three dimensions inside a crystal remain a challenge. Here, by using Bragg coherent diffraction imaging, we observe an unexpected anomalous {110} glide plane in two Pt submicrometer crystals grown by very different processes and having very different morphologies. The structure of the defects (type, associated glide plane, and lattice displacement) is imaged in these faceted Pt crystals. Using this noninvasive technique, both plasticity and unusual defect behavior can be probed at the nanoscale.",

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note = "Funding Information: The authors are grateful to ESRF (proposal HC4760) and PETRA (proposal 20180962EC) synchrotrons for allocating beamtime. The measurement was performed at the ID01 beamline of the European synchrotron (ESRF) and at the P10 beamline of the PETRA III synchrotron at DESY, a member of the Helmholtz Association (HGF). We thank the ID01 and P10 beamline staff for excellent support during the experiment. This project has received funding from the European Research Council (ERC) under the European Union{\textquoteright}s Horizon 2020 research and innovation programme (grant agreement No. 818823) and from the DINACS ANR project (ANR-21-CE08-0033-01). The research leading to this result has been supported by the project CALIPSOplus under the Grant Agreement 730872 from the EU Framework Programme for Research and Innovation HORIZON 2020. We also wish to thank the support by a grant from the Ministry of Science and Technology, Israel and from the Centre National de la Recherche Scientifique (CNRS), France. Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

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AU - Carnis, Jérôme

AU - Gao, Lu

AU - Texier, Michaël

AU - Li, Ni

AU - Wu, Longfei

AU - Hofmann, Jan P.

AU - Levi, Mor

AU - Leake, Steven J.

AU - Lazarev, Sergey

AU - Sprung, Michael

AU - Hensen, Emiel J.M.

AU - Rabkin, Eugen

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Anomalous Glide Plane in Platinum Nano- and Microcrystals

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Keywords

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