An emulsifier-free RAFT-mediated process for the efficient synthesis of cerium oxide/polymer hybrid latexes

J. Garnier; J. Warnant; P. Lacroix-Desmazes; P.E. Dufils; J. Vinas; Y. Vanderveken; A.M. Herk, van

doi:10.1002/marc.201200093

An emulsifier-free RAFT-mediated process for the efficient synthesis of cerium oxide/polymer hybrid latexes

J. Garnier, J. Warnant, P. Lacroix-Desmazes, P.E. Dufils, J. Vinas, Y. Vanderveken, A.M. Herk, van

Research output: Contribution to journal › Article › Academic › peer-review

28 Citations (Scopus)

Abstract

Hybrid latexes based on cerium oxide nanoparticles are synthesized via an emulsifier-free process of emulsion polymerization employing amphiphatic macro-RAFT agents. Poly(butyl acrylate-co-acrylic acid) random oligomers of various compositions and chain lengths are first obtained by RAFT copolymerization in the presence of a trithiocarbonate as controlling agent. In a second step, the seeded emulsion copolymerization of styrene and methyl acrylate is carried out in the presence of nanoceria with macro-RAFT agents adsorbed at their surface, resulting in a high incorporation efficiency of cerium oxide nanoparticles in the final hybrid latexes, as evidenced by cryo-transmission electron microscopy.

Original language	English
Pages (from-to)	1388-1392
Number of pages	5
Journal	Macromolecular Rapid Communications
Volume	33
Issue number	16
DOIs	https://doi.org/10.1002/marc.201200093
Publication status	Published - 2012

Access to Document

10.1002/marc.201200093

Cite this

@article{092b364f2adb4a6d98c449e9f26bf72a,

title = "An emulsifier-free RAFT-mediated process for the efficient synthesis of cerium oxide/polymer hybrid latexes",

abstract = "Hybrid latexes based on cerium oxide nanoparticles are synthesized via an emulsifier-free process of emulsion polymerization employing amphiphatic macro-RAFT agents. Poly(butyl acrylate-co-acrylic acid) random oligomers of various compositions and chain lengths are first obtained by RAFT copolymerization in the presence of a trithiocarbonate as controlling agent. In a second step, the seeded emulsion copolymerization of styrene and methyl acrylate is carried out in the presence of nanoceria with macro-RAFT agents adsorbed at their surface, resulting in a high incorporation efficiency of cerium oxide nanoparticles in the final hybrid latexes, as evidenced by cryo-transmission electron microscopy.",

author = "J. Garnier and J. Warnant and P. Lacroix-Desmazes and P.E. Dufils and J. Vinas and Y. Vanderveken and {Herk, van}, A.M.",

year = "2012",

doi = "10.1002/marc.201200093",

language = "English",

volume = "33",

pages = "1388--1392",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

number = "16",

}

TY - JOUR

T1 - An emulsifier-free RAFT-mediated process for the efficient synthesis of cerium oxide/polymer hybrid latexes

AU - Garnier, J.

AU - Warnant, J.

AU - Lacroix-Desmazes, P.

AU - Dufils, P.E.

AU - Vinas, J.

AU - Vanderveken, Y.

AU - Herk, van, A.M.

PY - 2012

Y1 - 2012

N2 - Hybrid latexes based on cerium oxide nanoparticles are synthesized via an emulsifier-free process of emulsion polymerization employing amphiphatic macro-RAFT agents. Poly(butyl acrylate-co-acrylic acid) random oligomers of various compositions and chain lengths are first obtained by RAFT copolymerization in the presence of a trithiocarbonate as controlling agent. In a second step, the seeded emulsion copolymerization of styrene and methyl acrylate is carried out in the presence of nanoceria with macro-RAFT agents adsorbed at their surface, resulting in a high incorporation efficiency of cerium oxide nanoparticles in the final hybrid latexes, as evidenced by cryo-transmission electron microscopy.

AB - Hybrid latexes based on cerium oxide nanoparticles are synthesized via an emulsifier-free process of emulsion polymerization employing amphiphatic macro-RAFT agents. Poly(butyl acrylate-co-acrylic acid) random oligomers of various compositions and chain lengths are first obtained by RAFT copolymerization in the presence of a trithiocarbonate as controlling agent. In a second step, the seeded emulsion copolymerization of styrene and methyl acrylate is carried out in the presence of nanoceria with macro-RAFT agents adsorbed at their surface, resulting in a high incorporation efficiency of cerium oxide nanoparticles in the final hybrid latexes, as evidenced by cryo-transmission electron microscopy.

U2 - 10.1002/marc.201200093

DO - 10.1002/marc.201200093

M3 - Article

C2 - 22605563

SN - 1022-1336

VL - 33

SP - 1388

EP - 1392

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 16

ER -

An emulsifier-free RAFT-mediated process for the efficient synthesis of cerium oxide/polymer hybrid latexes

Abstract

Access to Document

Fingerprint

Cite this