Alternation and tunable composition in hydrogen bonded supramolecular copolymers

T.M. Felder, T.F.A. Greef, de, M.M.L. Nieuwenhuizen, R.P. Sijbesma

Research output: Contribution to journalArticleAcademicpeer-review

16 Citations (Scopus)
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Abstract

Sequence control in supramolecular copolymers is limited by the selectivity of the associating monomer end groups. Here we introduce the use of monomers with aminopyrimidinone and aminohydroxynaphthyridine quadruple hydrogen bonding end groups, which both homodimerize, but form even stronger heterodimers. These features allow the formation of supramolecular copolymers with a tunable composition and a preference for alternating sequences.
Original languageEnglish
Pages (from-to)2455-2457
Number of pages3
JournalChemical Communications
Volume50
Issue number19
DOIs
Publication statusPublished - 2014

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