Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified Ï€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers

A. Winter; C. Friebe; M.D. Hager; U.S. Schubert

doi:10.1002/marc.200800377

Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified Ï€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers

A. Winter, C. Friebe, M.D. Hager, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

35 Citations (Scopus)

Abstract

A set of rigid Ï€-conjugated bis(terpyridine) macroligands with poly(+µ-caprolactone) (pCL) on their side chains was synthesized and investigated. The introduced pCL chains gave rise to enhanced processability and film-forming properties of the materials. Blue photoluminescence with high quantum yields was observed in dilute solution and in the solid state, indicating that intermolecular aggregation of the Ï€-conjugated systems was effectively suppressed. The macroligands were further used for coordination with zinc(II) ions leading to new metallo-polymers with high solubility, improved film-forming behavior and promising photo-physical properties with respect to potential OLED applications. -© 2008 WILEY-VCH Verlag GmbH & Co. KGaA

Original language	English
Pages (from-to)	1679-1686
Journal	Macromolecular Rapid Communications
Volume	29
Issue number	20
DOIs	https://doi.org/10.1002/marc.200800377
Publication status	Published - 2008

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10.1002/marc.200800377

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title = "Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified {\"I}€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers",

abstract = "A set of rigid {\"I}€-conjugated bis(terpyridine) macroligands with poly(+µ-caprolactone) (pCL) on their side chains was synthesized and investigated. The introduced pCL chains gave rise to enhanced processability and film-forming properties of the materials. Blue photoluminescence with high quantum yields was observed in dilute solution and in the solid state, indicating that intermolecular aggregation of the {\"I}€-conjugated systems was effectively suppressed. The macroligands were further used for coordination with zinc(II) ions leading to new metallo-polymers with high solubility, improved film-forming behavior and promising photo-physical properties with respect to potential OLED applications. -{\textcopyright} 2008 WILEY-VCH Verlag GmbH & Co. KGaA",

author = "A. Winter and C. Friebe and M.D. Hager and U.S. Schubert",

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pages = "1679--1686",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

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}

Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified Ï€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers. / Winter, A.; Friebe, C.; Hager, M.D. et al.
In: Macromolecular Rapid Communications, Vol. 29, No. 20, 2008, p. 1679-1686.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified Ï€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers

AU - Winter, A.

AU - Friebe, C.

AU - Hager, M.D.

AU - Schubert, U.S.

PY - 2008

Y1 - 2008

N2 - A set of rigid Ï€-conjugated bis(terpyridine) macroligands with poly(+µ-caprolactone) (pCL) on their side chains was synthesized and investigated. The introduced pCL chains gave rise to enhanced processability and film-forming properties of the materials. Blue photoluminescence with high quantum yields was observed in dilute solution and in the solid state, indicating that intermolecular aggregation of the Ï€-conjugated systems was effectively suppressed. The macroligands were further used for coordination with zinc(II) ions leading to new metallo-polymers with high solubility, improved film-forming behavior and promising photo-physical properties with respect to potential OLED applications. -© 2008 WILEY-VCH Verlag GmbH & Co. KGaA

AB - A set of rigid Ï€-conjugated bis(terpyridine) macroligands with poly(+µ-caprolactone) (pCL) on their side chains was synthesized and investigated. The introduced pCL chains gave rise to enhanced processability and film-forming properties of the materials. Blue photoluminescence with high quantum yields was observed in dilute solution and in the solid state, indicating that intermolecular aggregation of the Ï€-conjugated systems was effectively suppressed. The macroligands were further used for coordination with zinc(II) ions leading to new metallo-polymers with high solubility, improved film-forming behavior and promising photo-physical properties with respect to potential OLED applications. -© 2008 WILEY-VCH Verlag GmbH & Co. KGaA

U2 - 10.1002/marc.200800377

DO - 10.1002/marc.200800377

M3 - Article

SN - 1022-1336

VL - 29

SP - 1679

EP - 1686

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 20

ER -

Advancing the solid state properties of metallo-supramolecular materials: Poly(+µ-caprolactone) modified Ï€-conjugated bis(terpyridine)s and their Zn(II) based metallo-polymers

Abstract

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