Adsorption studies on ordered mesoporous materials (MCM-41)

J.J. Jänchen; M.C.M. Busio; M. Hintze; H. Stach; J.H.C. Hooff, van

doi:10.1016/S0167-2991(97)80637-4

Adsorption studies on ordered mesoporous materials (MCM-41)

J.J. Jänchen, M.C.M. Busio, M. Hintze, H. Stach, J.H.C. Hooff, van

Inorganic Materials & Catalysis

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

17 Citations (Scopus)

Abstract

Ordered mesoporous materials, MCM-41, with varying Si/Al ratios have been synthesised and characterised by adsorption, XRD, NMR, and FTIR measurements. 27Al MAS NMR shows four-fold co-ordination of Al incorporated into the structure. The combined study by microcalorimetry and FTIR, using acetonitrile as probe shows a few strong Lewis sites and only weak Brønsted acidity. The physisorption properties were analysed by N2, n-hexane, benzene, acetonitrile, methanol and water adsorption using microcalorimetry and isotherm measurements. MCM-41 shows adsorption behaviour of a well-defined mesoporous molecular sieve. The heat of adsorption of a non-polar molecule is mainly determined by the pore diameter of the porous material. A characteristic feature of all applied adsorptives is capillary condensation. Whereas isotherms of water are completely irreversible and acetonitrile shows a small hysteresis, isotherms of the non-polar benzene, n-hexane, and nitrogen are completely reversible.

Original language	English
Title of host publication	Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996
Editors	H. Chon
Place of Publication	Amsterdam
Publisher	Elsevier
Pages	1731-1738
ISBN (Print)	0-444-82344-1
DOIs	https://doi.org/10.1016/S0167-2991(97)80637-4
Publication status	Published - 1996
Event	11th International Zeolite conference - Seoul, Korea, Democratic People's Republic of Duration: 12 Aug 1996 → 17 Aug 1996 Conference number: 11

Publication series

Name	Studies in Surface Science and Catalysis
Volume	105
ISSN (Print)	0167-2991

Conference

Conference	11th International Zeolite conference
Abbreviated title	IZC
Country/Territory	Korea, Democratic People's Republic of
City	Seoul
Period	12/08/96 → 17/08/96
Other	11th International Zeolite conference, Seoul, Korea, 12-17-August 1996

Access to Document

10.1016/S0167-2991(97)80637-4

Cite this

Jänchen, J. J., Busio, M. C. M., Hintze, M., Stach, H., & Hooff, van, J. H. C. (1996). Adsorption studies on ordered mesoporous materials (MCM-41). In H. Chon (Ed.), Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996 (pp. 1731-1738). (Studies in Surface Science and Catalysis; Vol. 105). Elsevier. https://doi.org/10.1016/S0167-2991(97)80637-4

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title = "Adsorption studies on ordered mesoporous materials (MCM-41)",

abstract = "Ordered mesoporous materials, MCM-41, with varying Si/Al ratios have been synthesised and characterised by adsorption, XRD, NMR, and FTIR measurements. 27Al MAS NMR shows four-fold co-ordination of Al incorporated into the structure. The combined study by microcalorimetry and FTIR, using acetonitrile as probe shows a few strong Lewis sites and only weak Br{\o}nsted acidity. The physisorption properties were analysed by N2, n-hexane, benzene, acetonitrile, methanol and water adsorption using microcalorimetry and isotherm measurements. MCM-41 shows adsorption behaviour of a well-defined mesoporous molecular sieve. The heat of adsorption of a non-polar molecule is mainly determined by the pore diameter of the porous material. A characteristic feature of all applied adsorptives is capillary condensation. Whereas isotherms of water are completely irreversible and acetonitrile shows a small hysteresis, isotherms of the non-polar benzene, n-hexane, and nitrogen are completely reversible.",

author = "J.J. J{\"a}nchen and M.C.M. Busio and M. Hintze and H. Stach and {Hooff, van}, J.H.C.",

year = "1996",

doi = "10.1016/S0167-2991(97)80637-4",

language = "English",

isbn = "0-444-82344-1",

series = "Studies in Surface Science and Catalysis",

publisher = "Elsevier",

pages = "1731--1738",

editor = "H. Chon",

booktitle = "Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996",

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note = "11th International Zeolite conference, IZC ; Conference date: 12-08-1996 Through 17-08-1996",

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Jänchen, JJ, Busio, MCM, Hintze, M, Stach, H & Hooff, van, JHC 1996, Adsorption studies on ordered mesoporous materials (MCM-41). in H Chon (ed.), Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996. Studies in Surface Science and Catalysis, vol. 105, Elsevier, Amsterdam, pp. 1731-1738, 11th International Zeolite conference, Seoul, Korea, Democratic People's Republic of, 12/08/96. https://doi.org/10.1016/S0167-2991(97)80637-4

Adsorption studies on ordered mesoporous materials (MCM-41). / Jänchen, J.J.; Busio, M.C.M.; Hintze, M. et al.

Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996. ed. / H. Chon. Amsterdam : Elsevier, 1996. p. 1731-1738 (Studies in Surface Science and Catalysis; Vol. 105).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › Academic

TY - GEN

T1 - Adsorption studies on ordered mesoporous materials (MCM-41)

AU - Jänchen, J.J.

AU - Busio, M.C.M.

AU - Hintze, M.

AU - Stach, H.

AU - Hooff, van, J.H.C.

N1 - Conference code: 11

PY - 1996

Y1 - 1996

N2 - Ordered mesoporous materials, MCM-41, with varying Si/Al ratios have been synthesised and characterised by adsorption, XRD, NMR, and FTIR measurements. 27Al MAS NMR shows four-fold co-ordination of Al incorporated into the structure. The combined study by microcalorimetry and FTIR, using acetonitrile as probe shows a few strong Lewis sites and only weak Brønsted acidity. The physisorption properties were analysed by N2, n-hexane, benzene, acetonitrile, methanol and water adsorption using microcalorimetry and isotherm measurements. MCM-41 shows adsorption behaviour of a well-defined mesoporous molecular sieve. The heat of adsorption of a non-polar molecule is mainly determined by the pore diameter of the porous material. A characteristic feature of all applied adsorptives is capillary condensation. Whereas isotherms of water are completely irreversible and acetonitrile shows a small hysteresis, isotherms of the non-polar benzene, n-hexane, and nitrogen are completely reversible.

AB - Ordered mesoporous materials, MCM-41, with varying Si/Al ratios have been synthesised and characterised by adsorption, XRD, NMR, and FTIR measurements. 27Al MAS NMR shows four-fold co-ordination of Al incorporated into the structure. The combined study by microcalorimetry and FTIR, using acetonitrile as probe shows a few strong Lewis sites and only weak Brønsted acidity. The physisorption properties were analysed by N2, n-hexane, benzene, acetonitrile, methanol and water adsorption using microcalorimetry and isotherm measurements. MCM-41 shows adsorption behaviour of a well-defined mesoporous molecular sieve. The heat of adsorption of a non-polar molecule is mainly determined by the pore diameter of the porous material. A characteristic feature of all applied adsorptives is capillary condensation. Whereas isotherms of water are completely irreversible and acetonitrile shows a small hysteresis, isotherms of the non-polar benzene, n-hexane, and nitrogen are completely reversible.

U2 - 10.1016/S0167-2991(97)80637-4

DO - 10.1016/S0167-2991(97)80637-4

M3 - Conference contribution

SN - 0-444-82344-1

T3 - Studies in Surface Science and Catalysis

SP - 1731

EP - 1738

BT - Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996

A2 - Chon, H.

PB - Elsevier

CY - Amsterdam

T2 - 11th International Zeolite conference

Y2 - 12 August 1996 through 17 August 1996

ER -

Jänchen JJ, Busio MCM, Hintze M, Stach H, Hooff, van JHC. Adsorption studies on ordered mesoporous materials (MCM-41). In Chon H, editor, Progress in zeolite and microporous materials : proceedings of the 11th International Zeolite Conference, Seoul, Korea, August 12-17, 1996. Amsterdam: Elsevier. 1996. p. 1731-1738. (Studies in Surface Science and Catalysis). doi: 10.1016/S0167-2991(97)80637-4

Adsorption studies on ordered mesoporous materials (MCM-41)

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