Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

M. Mihaylov, K. Chakarova, S. Andonova, N. Drenchev, E. Ivanova, E.A. Pidko, A. Sabetghadam, B. Seoane, J. Gascon, F. Kapteijn, K. Hadjiivanov

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Abstract

FTIR spectra of 12CO2 and 12CO2 + 13CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.

Original languageEnglish
Pages (from-to)1494-1497
Number of pages4
JournalChemical Communications
Volume52
Issue number7
DOIs
Publication statusPublished - 25 Jan 2016

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