Activation of co–mo–S hydrodesulfurization catalysts under refinery conditions: a combined SAXS/XAS study

Lennart van Haandel, Alessandro Longo, Wim Bras, Emiel J.M. Hensen, Thomas Weber (Corresponding author)

Research output: Contribution to journalArticleAcademicpeer-review

2 Citations (Scopus)
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Abstract

The activation of heterogeneous catalysts is challenging to follow experimentally and poorly understood in many cases. We combine in situ and time‐resolved X‐ray absorption spectroscopy and small‐angle X‐ray scattering to study the activation of Co‐Mo−S hydrotreating catalysts under conditions close to a refinery start‐up, i. e., 20 bar H2 pressure and gaseous H2S or liquid sulfiding agents. Formation of MoS2 nanoparticles involves three stages, namely aggregation (50–150 °C) and self‐assembly (150–250 °C) of two distinct amorphous MoSx intermediates, followed by a transition into layered structures that closely relate to the MoS2 structure. In stage III, these nuclei coalesce into the final MoS2 nanoparticles. Their growth distribution and stacking degree can be tailored by controlling the aggregation step, paving the way for the synthesis of better hydrotreating catalysts. Our experimental approach enables studying a broad range of supported amorphous nanomaterials at various length scales and operating conditions relevant to important catalytic processes.
Original languageEnglish
Pages (from-to)5013-5017
Number of pages5
JournalChemCatChem
Volume11
Issue number20
DOIs
Publication statusPublished - 18 Oct 2019

Keywords

  • EXAFS
  • Heterogeneous catalyst
  • Hydrodesulfurization
  • Nanoparticle formation
  • SAXS

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