TY - JOUR
T1 - Ab initio band structure calculations of the low-temperature phases of Ag2Se, Ag2Te and Ag3AuSe2.
AU - Fang, C.M.
AU - Groot, de, R.A.
AU - Wiegers, G.A.
PY - 2002
Y1 - 2002
N2 - Ab initio band structure calculations were performed for the low-temperature modifications of the silver chalcogenides B-Ag2Se, B-Ag2Te and the ternary compound B-Ag3AuSe2 by the local spherical wave (LSW)method. Coordinated of the atoms of B-Ag2Se and B-Ag3AuSe2 were obtained from refinements using X-ray powder data. The structures are characterized by three, four and five coordinates of silver by the chalcogen, a linear coordination of gold by Se, and by metal-metal distances only slightly larger than in the metals. The band structure calculations show that B-Ag3AuSe2 is a semiconductor, while B-Ag2Se and B-Ag2Te are semimetals with an overlap of about 0.1-0.2 eV. The Ag 4d and Au 5d states are strongly hybridized with the chalcogen p states all over the valence bands. B-Ag2Se and B-Ag2Te have a very low DOS in the energy range from about -0.1 To +0.5 eV. The calculated effective mass B-Ag2Se is about 0.1-0.3 Me for electrons and 0.75 Me for holes, respectively.
AB - Ab initio band structure calculations were performed for the low-temperature modifications of the silver chalcogenides B-Ag2Se, B-Ag2Te and the ternary compound B-Ag3AuSe2 by the local spherical wave (LSW)method. Coordinated of the atoms of B-Ag2Se and B-Ag3AuSe2 were obtained from refinements using X-ray powder data. The structures are characterized by three, four and five coordinates of silver by the chalcogen, a linear coordination of gold by Se, and by metal-metal distances only slightly larger than in the metals. The band structure calculations show that B-Ag3AuSe2 is a semiconductor, while B-Ag2Se and B-Ag2Te are semimetals with an overlap of about 0.1-0.2 eV. The Ag 4d and Au 5d states are strongly hybridized with the chalcogen p states all over the valence bands. B-Ag2Se and B-Ag2Te have a very low DOS in the energy range from about -0.1 To +0.5 eV. The calculated effective mass B-Ag2Se is about 0.1-0.3 Me for electrons and 0.75 Me for holes, respectively.
U2 - 10.1016/S0022-3697(01)00160-3
DO - 10.1016/S0022-3697(01)00160-3
M3 - Article
SN - 0022-3697
VL - 63
SP - 457
EP - 464
JO - Journal of Physics and Chemistry of Solids
JF - Journal of Physics and Chemistry of Solids
IS - 3
ER -