A selectivity-driven supramolecular polymerization of an AB monomer

O.A. Scherman; G.B.W.L. Ligthart; R.P. Sijbesma; E.W. Meijer

doi:10.1002/anie.200504192

A selectivity-driven supramolecular polymerization of an AB monomer

O.A. Scherman
, G.B.W.L. Ligthart
, R.P. Sijbesma
, E.W. Meijer

Research output: Contribution to journal › Article › Academic › peer-review

127 Citations (Scopus)

Abstract

Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.

Original language	English
Pages (from-to)	2072-2076
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	13
DOIs	https://doi.org/10.1002/anie.200504192
Publication status	Published - 2006

Access to Document

10.1002/anie.200504192

Cite this

@article{c03f5e4aa527411f909ed3edda42aa33,

title = "A selectivity-driven supramolecular polymerization of an AB monomer",

abstract = "Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.",

author = "O.A. Scherman and G.B.W.L. Ligthart and R.P. Sijbesma and E.W. Meijer",

year = "2006",

doi = "10.1002/anie.200504192",

language = "English",

volume = "45",

pages = "2072--2076",

journal = "Angewandte Chemie - International Edition",

issn = "0570-0833",

publisher = "Wiley",

number = "13",

}

TY - JOUR

T1 - A selectivity-driven supramolecular polymerization of an AB monomer

AU - Scherman, O.A.

AU - Ligthart, G.B.W.L.

AU - Sijbesma, R.P.

AU - Meijer, E.W.

PY - 2006

Y1 - 2006

N2 - Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.

AB - Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.

U2 - 10.1002/anie.200504192

DO - 10.1002/anie.200504192

M3 - Article

C2 - 16502447

SN - 0570-0833

VL - 45

SP - 2072

EP - 2076

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13

ER -

A selectivity-driven supramolecular polymerization of an AB monomer

Abstract

Access to Document

Fingerprint

Cite this