TY - JOUR
T1 - A selectivity-driven supramolecular polymerization of an AB monomer
AU - Scherman, O.A.
AU - Ligthart, G.B.W.L.
AU - Sijbesma, R.P.
AU - Meijer, E.W.
PY - 2006
Y1 - 2006
N2 - Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.
AB - Two become one: An AB-type monomer containing both 2-ureido-4[1H]-pyrimidinone and 2,7-diamido-1,8-naphthyridine quadruple hydrogen-bonding moieties is obtained by selective olefin cross metathesis. This monomer addresses the issue of stoichiometric imbalance in the self-assembly of AA+BB-type supramolecular polymers. Moreover, as the linker between both motifs is quite flexible, this monomer exists as a monocycle at low concentrations.
U2 - 10.1002/anie.200504192
DO - 10.1002/anie.200504192
M3 - Article
C2 - 16502447
SN - 0570-0833
VL - 45
SP - 2072
EP - 2076
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 13
ER -