A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Z.O. Oyman, W. Ming, F. Micciche, E. Oostveen, J. Haveren, van, R. Linde, van der

Research output: Contribution to journalArticleAcademicpeer-review

38 Citations (Scopus)

Abstract

A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.
Original languageEnglish
Pages (from-to)7431-7436
JournalPolymer
Volume45
Issue number22
DOIs
Publication statusPublished - 2004

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