A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Z.O. Oyman; W. Ming; F. Micciche; E. Oostveen; J. Haveren, van; R. Linde, van der

doi:10.1016/j.polymer.2004.08.052

A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Z.O. Oyman, W. Ming, F. Micciche, E. Oostveen, J. Haveren, van, R. Linde, van der

Materials and Interface Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

Original language	English
Pages (from-to)	7431-7436
Journal	Polymer
Volume	45
Issue number	22
DOIs	https://doi.org/10.1016/j.polymer.2004.08.052
Publication status	Published - 2004

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title = "A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings",

abstract = "A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.",

author = "Z.O. Oyman and W. Ming and F. Micciche and E. Oostveen and {Haveren, van}, J. and {Linde, van der}, R.",

year = "2004",

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language = "English",

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journal = "Polymer",

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T1 - A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

AU - Oyman, Z.O.

AU - Ming, W.

AU - Micciche, F.

AU - Oostveen, E.

AU - Haveren, van, J.

AU - Linde, van der, R.

PY - 2004

Y1 - 2004

N2 - A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

AB - A manganese(IV) complex (MnMeTACN) containing 1,4,7-trimethyl-1,4,7-triazacyclononane (MeTACN), in the presence of polyamines, significantly accelerated the oxidation of ethyl linoleate (EL) emulsions, and appeared to be a potential environmentally-friendly alternative for Co-based driers that are currently widely used for alkyd emulsion coatings. The polyamines greatly enhanced the catalytic activity of MnMeTACN in decomposing the formed hydroperoxides during the oxidation of EL.

U2 - 10.1016/j.polymer.2004.08.052

DO - 10.1016/j.polymer.2004.08.052

M3 - Article

SN - 0032-3861

VL - 45

SP - 7431

EP - 7436

JO - Polymer

JF - Polymer

IS - 22

ER -

A promising environmentally-friendly manganese-based catalyst for alkyd emulsion coatings

Abstract

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