A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly(ethylene glycol) macroligand

E. Holder; V.N. Marin; M.A.R. Meier; U.S. Schubert

doi:10.1002/marc.200400206

A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly(ethylene glycol) macroligand

E. Holder, V.N. Marin, M.A.R. Meier, U.S. Schubert

Chemical Engineering and Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

45 Citations (Scopus)

Abstract

A monoterpyridine-poly(ethylene glycol) (mono-tpy-PEG) and a novel monoterpyridine-PEG-functionalized iridium(III) complex were successfully synthesized and fully characterized by means of NMR, IR, and UV-vis spectroscopy, as well as gel permeation chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The functionalized monoterpyridine iridium(III) complex was synthesized by a bridge-splitting reaction of a dimeric iridium(III) precursor complex using a chelating terpyridine ligand with a poly(ethylene glycol) tail. With this approach, a new class of light-emitting polymeric materials revealing interesting optical properties was made avaialable.

Original language	English
Pages (from-to)	1491-1496
Journal	Macromolecular Rapid Communications
Volume	25
Issue number	16
DOIs	https://doi.org/10.1002/marc.200400206
Publication status	Published - 2004

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title = "A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly(ethylene glycol) macroligand",

abstract = "A monoterpyridine-poly(ethylene glycol) (mono-tpy-PEG) and a novel monoterpyridine-PEG-functionalized iridium(III) complex were successfully synthesized and fully characterized by means of NMR, IR, and UV-vis spectroscopy, as well as gel permeation chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The functionalized monoterpyridine iridium(III) complex was synthesized by a bridge-splitting reaction of a dimeric iridium(III) precursor complex using a chelating terpyridine ligand with a poly(ethylene glycol) tail. With this approach, a new class of light-emitting polymeric materials revealing interesting optical properties was made avaialable.",

author = "E. Holder and V.N. Marin and M.A.R. Meier and U.S. Schubert",

year = "2004",

doi = "10.1002/marc.200400206",

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pages = "1491--1496",

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T1 - A novel light-emitting mixed-ligand iridium(III) complex with a terpyridine-poly(ethylene glycol) macroligand

AU - Holder, E.

AU - Marin, V.N.

AU - Meier, M.A.R.

AU - Schubert, U.S.

PY - 2004

Y1 - 2004

N2 - A monoterpyridine-poly(ethylene glycol) (mono-tpy-PEG) and a novel monoterpyridine-PEG-functionalized iridium(III) complex were successfully synthesized and fully characterized by means of NMR, IR, and UV-vis spectroscopy, as well as gel permeation chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The functionalized monoterpyridine iridium(III) complex was synthesized by a bridge-splitting reaction of a dimeric iridium(III) precursor complex using a chelating terpyridine ligand with a poly(ethylene glycol) tail. With this approach, a new class of light-emitting polymeric materials revealing interesting optical properties was made avaialable.

AB - A monoterpyridine-poly(ethylene glycol) (mono-tpy-PEG) and a novel monoterpyridine-PEG-functionalized iridium(III) complex were successfully synthesized and fully characterized by means of NMR, IR, and UV-vis spectroscopy, as well as gel permeation chromatography and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. The functionalized monoterpyridine iridium(III) complex was synthesized by a bridge-splitting reaction of a dimeric iridium(III) precursor complex using a chelating terpyridine ligand with a poly(ethylene glycol) tail. With this approach, a new class of light-emitting polymeric materials revealing interesting optical properties was made avaialable.

U2 - 10.1002/marc.200400206

DO - 10.1002/marc.200400206

M3 - Article

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EP - 1496

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

SN - 1022-1336

IS - 16

ER -