A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5

G. Boxhoorn, R.A. Santen, van, W.A. Erp, van, G.R. Hays, N.C.M. Alma, R. Huis, A.D.H. Clague

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Abstract

A no. of ZSM-5 and ZSM-11 zeolites were studied by using 13C and 29Si solid-state magic-angle-spinning NMR. The study confirmed the presence of occluded org. cations at the intersections of the 10-ring channels in the zeolite. Incorporated Pr4N+ cations exhibit a particular splitting of Me resonance, which is related to the ZSM-5 channel structure. The nature of 29Si NMR spectra of HZSM-5 strongly depends on the presence of silanol groups in defect positions in the zeolite lattice
Original languageEnglish
Title of host publicationProceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London
EditorsG.C. Bond, P.B. Wells, F.C. Tompkins
Place of PublicationLondon
PublisherChemical Society
Pages694-703
ISBN (Print)0-85186-188-1
Publication statusPublished - 1983

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Zeolites
Silicon
Carbon
Nuclear magnetic resonance
Cations
Magic angle spinning
Defects

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Boxhoorn, G., Santen, van, R. A., Erp, van, W. A., Hays, G. R., Alma, N. C. M., Huis, R., & Clague, A. D. H. (1983). A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5. In G. C. Bond, P. B. Wells, & F. C. Tompkins (Eds.), Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London (pp. 694-703). London: Chemical Society.
Boxhoorn, G. ; Santen, van, R.A. ; Erp, van, W.A. ; Hays, G.R. ; Alma, N.C.M. ; Huis, R. ; Clague, A.D.H. / A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5. Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London. editor / G.C. Bond ; P.B. Wells ; F.C. Tompkins. London : Chemical Society, 1983. pp. 694-703
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abstract = "A no. of ZSM-5 and ZSM-11 zeolites were studied by using 13C and 29Si solid-state magic-angle-spinning NMR. The study confirmed the presence of occluded org. cations at the intersections of the 10-ring channels in the zeolite. Incorporated Pr4N+ cations exhibit a particular splitting of Me resonance, which is related to the ZSM-5 channel structure. The nature of 29Si NMR spectra of HZSM-5 strongly depends on the presence of silanol groups in defect positions in the zeolite lattice",
author = "G. Boxhoorn and {Santen, van}, R.A. and {Erp, van}, W.A. and G.R. Hays and N.C.M. Alma and R. Huis and A.D.H. Clague",
year = "1983",
language = "English",
isbn = "0-85186-188-1",
pages = "694--703",
editor = "G.C. Bond and P.B. Wells and F.C. Tompkins",
booktitle = "Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London",
publisher = "Chemical Society",
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Boxhoorn, G, Santen, van, RA, Erp, van, WA, Hays, GR, Alma, NCM, Huis, R & Clague, ADH 1983, A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5. in GC Bond, PB Wells & FC Tompkins (eds), Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London. Chemical Society, London, pp. 694-703.

A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5. / Boxhoorn, G.; Santen, van, R.A.; Erp, van, W.A.; Hays, G.R.; Alma, N.C.M.; Huis, R.; Clague, A.D.H.

Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London. ed. / G.C. Bond; P.B. Wells; F.C. Tompkins. London : Chemical Society, 1983. p. 694-703.

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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T1 - A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5

AU - Boxhoorn, G.

AU - Santen, van, R.A.

AU - Erp, van, W.A.

AU - Hays, G.R.

AU - Alma, N.C.M.

AU - Huis, R.

AU - Clague, A.D.H.

PY - 1983

Y1 - 1983

N2 - A no. of ZSM-5 and ZSM-11 zeolites were studied by using 13C and 29Si solid-state magic-angle-spinning NMR. The study confirmed the presence of occluded org. cations at the intersections of the 10-ring channels in the zeolite. Incorporated Pr4N+ cations exhibit a particular splitting of Me resonance, which is related to the ZSM-5 channel structure. The nature of 29Si NMR spectra of HZSM-5 strongly depends on the presence of silanol groups in defect positions in the zeolite lattice

AB - A no. of ZSM-5 and ZSM-11 zeolites were studied by using 13C and 29Si solid-state magic-angle-spinning NMR. The study confirmed the presence of occluded org. cations at the intersections of the 10-ring channels in the zeolite. Incorporated Pr4N+ cations exhibit a particular splitting of Me resonance, which is related to the ZSM-5 channel structure. The nature of 29Si NMR spectra of HZSM-5 strongly depends on the presence of silanol groups in defect positions in the zeolite lattice

M3 - Conference contribution

SN - 0-85186-188-1

SP - 694

EP - 703

BT - Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London

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A2 - Tompkins, F.C.

PB - Chemical Society

CY - London

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Boxhoorn G, Santen, van RA, Erp, van WA, Hays GR, Alma NCM, Huis R et al. A high-resolution solid-state carbon-13 NMR investigation of occluded templates in pentasil-type zeolites : some silicon-29 solid-state NMR characteristics of ZSM-5. In Bond GC, Wells PB, Tompkins FC, editors, Proceedings of the Sixth International Congress on Catalysis (ICC 6) 12 - 16 July, 1976, Imperial College, London. London: Chemical Society. 1983. p. 694-703