A fast method to compute the MSD and MWD of polymer populations formed by step-growth polymerization of polyfunctional monomers bearing A and B coreactive groups

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Abstract

For step-growth polymer systems of general type "AfiBgi", a fast method is derived to compute the MSD and the MWD. The figure shows the full MWD curves of system "A1B1¿+¿B1¿+¿A2¿+¿B3" with pA[gel]¿=¿0.969877 at pA¿=¿0.964, 0.967, 0.969. Blue: calculated using recurrence scheme. Red: calculated using analytic approximation.
Original languageEnglish
Pages (from-to)553-564
JournalMacromolecular Theory and Simulations
Volume21
Issue number8
DOIs
Publication statusPublished - 2012

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Bearings (structural)
Polymers
Gels
polymerization
monomers
Monomers
Polymerization
gels
polymers
curves
approximation

Cite this

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title = "A fast method to compute the MSD and MWD of polymer populations formed by step-growth polymerization of polyfunctional monomers bearing A and B coreactive groups",
abstract = "For step-growth polymer systems of general type {"}AfiBgi{"}, a fast method is derived to compute the MSD and the MWD. The figure shows the full MWD curves of system {"}A1B1¿+¿B1¿+¿A2¿+¿B3{"} with pA[gel]¿=¿0.969877 at pA¿=¿0.964, 0.967, 0.969. Blue: calculated using recurrence scheme. Red: calculated using analytic approximation.",
author = "L.T.M.E. Hillegers and A. Blokhuis and J.J.M. Slot",
year = "2012",
doi = "10.1002/mats.201200027",
language = "English",
volume = "21",
pages = "553--564",
journal = "Macromolecular Theory and Simulations",
issn = "1022-1344",
publisher = "Wiley-VCH Verlag",
number = "8",

}

TY - JOUR

T1 - A fast method to compute the MSD and MWD of polymer populations formed by step-growth polymerization of polyfunctional monomers bearing A and B coreactive groups

AU - Hillegers, L.T.M.E.

AU - Blokhuis, A.

AU - Slot, J.J.M.

PY - 2012

Y1 - 2012

N2 - For step-growth polymer systems of general type "AfiBgi", a fast method is derived to compute the MSD and the MWD. The figure shows the full MWD curves of system "A1B1¿+¿B1¿+¿A2¿+¿B3" with pA[gel]¿=¿0.969877 at pA¿=¿0.964, 0.967, 0.969. Blue: calculated using recurrence scheme. Red: calculated using analytic approximation.

AB - For step-growth polymer systems of general type "AfiBgi", a fast method is derived to compute the MSD and the MWD. The figure shows the full MWD curves of system "A1B1¿+¿B1¿+¿A2¿+¿B3" with pA[gel]¿=¿0.969877 at pA¿=¿0.964, 0.967, 0.969. Blue: calculated using recurrence scheme. Red: calculated using analytic approximation.

U2 - 10.1002/mats.201200027

DO - 10.1002/mats.201200027

M3 - Article

VL - 21

SP - 553

EP - 564

JO - Macromolecular Theory and Simulations

JF - Macromolecular Theory and Simulations

SN - 1022-1344

IS - 8

ER -