@inbook{0d4d82f208d146298ac58e756cf003e2,
title = "A combined experimental and computational study of alkane activation over Ga+, GaO+, GaH2+ and H+ ion in ZSM-5",
abstract = "Replacement of Bronsted acid protons in zeolites by Ga ions shifts the mechanism of hydrocarbon conversion from protolytic cracking (C-H and C-C bond cleavage) to exclusive C-H bond cleavage via heterolytic dissocn. Charge-compensating GaO+ ions are more active than Ga+ ones but the former deactivate slowly due to decompn. to the latter under the reductive reactions conditions. Gallium-contg. zeolites are able to selectively convert propane to propylene.",
author = "E.J.M. Hensen and N.J. Rane and E.A. Pidko and {van Santen}, R.A.",
year = "2007",
doi = "10.1016/B978-0-444-53202-2.50093-2",
language = "English",
isbn = "978-0-444-53202-2",
series = "Studies in Surface Science and Catalysis",
publisher = "Elsevier",
pages = "417--420",
editor = "Koichi Eguchi and Masato Machida and Ichiro Yamanaka",
booktitle = "Science and Technology in Catalysis 2006",
address = "Netherlands",
}