A Chemical Alternative to Natural Gas Flaring

M. Golombok; W. Teunissen

doi:10.1021/ie0303808

A Chemical Alternative to Natural Gas Flaring

M. Golombok, W. Teunissen

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Abstract

A novel chemical liquefaction conversion process for one-step synthesis of natural gas to a methanol/acetic acid mixture is described. Previously reported homogeneous catalytic systems for carrying out methane coupling to CO2 are shown to work equally effectively with just methane. 13C labeling studies show that both carbons in the acetic acid originate from the methane. The reaction is therefore one of auto-oxidative coupling. The true yield is lower than previously claimed because the solubility of methane in the solvent needs to be taken into account.

Original language	English
Pages (from-to)	5003-5006
Journal	Industrial and Engineering Chemistry Research
Volume	42
Issue number	20
DOIs	https://doi.org/10.1021/ie0303808
Publication status	Published - 2003

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10.1021/ie0303808

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title = "A Chemical Alternative to Natural Gas Flaring",

abstract = "A novel chemical liquefaction conversion process for one-step synthesis of natural gas to a methanol/acetic acid mixture is described. Previously reported homogeneous catalytic systems for carrying out methane coupling to CO2 are shown to work equally effectively with just methane. 13C labeling studies show that both carbons in the acetic acid originate from the methane. The reaction is therefore one of auto-oxidative coupling. The true yield is lower than previously claimed because the solubility of methane in the solvent needs to be taken into account.",

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AB - A novel chemical liquefaction conversion process for one-step synthesis of natural gas to a methanol/acetic acid mixture is described. Previously reported homogeneous catalytic systems for carrying out methane coupling to CO2 are shown to work equally effectively with just methane. 13C labeling studies show that both carbons in the acetic acid originate from the methane. The reaction is therefore one of auto-oxidative coupling. The true yield is lower than previously claimed because the solubility of methane in the solvent needs to be taken into account.

U2 - 10.1021/ie0303808

DO - 10.1021/ie0303808

M3 - Article

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SP - 5003

EP - 5006

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

SN - 0888-5885

IS - 20

ER -

A Chemical Alternative to Natural Gas Flaring

Abstract

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