A 13C-NMR study of squalene, part II : functionalized squalene-like compounds

M.E. van Dommelen, L.J.M. Ven, van de, H.M. Buck, J.W. Haan, de

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Abstract

13C-NMR chemical shifts of substituted squalenes and model compounds with a heteroatom in d-position to a double bond show that a steric interaction exists between the hetero-atom and the double bond. This points to the presence of "precoiled" conformations in the hetero-substituted squalenes and also in squalene itself. The nature of the interaction remains veiled, but it appears to be a general feature as is shown in a series of 2- and 3-substituted thiophenes with a double bond in the side chain.
Original languageEnglish
Pages (from-to)295-301
JournalRecueil des Travaux Chimiques des Pays-Bas
Volume96
Issue number12
DOIs
Publication statusPublished - 1977

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