TY - JOUR
T1 - 4-(p-Methylthio)phenyl-2,6-diphenyl phosphinine: The first X-ray crystal structure of a λ3-triaryl-phosphabenzene
AU - Müller, C.
AU - Lutz, M.
AU - Spek, A.L.
AU - Vogt, D.
PY - 2006
Y1 - 2006
N2 - The new donor functionalized methylthio-phosphabenzene 3 was synthesized by reaction of the corresponding pyrylium salt with P(SiMe3)3. This compound was characterized crystallographically, showing eight independent molecules in the asymmetric unit. 3 crystallized in the orthorhombic space group Pna21 (no. 33) with cell parameters a=48.3565(8) Å, b=7.64784(7) Å, c=40.8432(4) Å, V=15104.7(3) Å3. This result represents the first crystal structure analysis of a ¿3-triaryl-phosphabenzene
AB - The new donor functionalized methylthio-phosphabenzene 3 was synthesized by reaction of the corresponding pyrylium salt with P(SiMe3)3. This compound was characterized crystallographically, showing eight independent molecules in the asymmetric unit. 3 crystallized in the orthorhombic space group Pna21 (no. 33) with cell parameters a=48.3565(8) Å, b=7.64784(7) Å, c=40.8432(4) Å, V=15104.7(3) Å3. This result represents the first crystal structure analysis of a ¿3-triaryl-phosphabenzene
U2 - 10.1007/s10870-006-9147-8
DO - 10.1007/s10870-006-9147-8
M3 - Article
SN - 1074-1542
VL - 36
SP - 869
EP - 874
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 12
ER -