3-D Nanoscale organization of bulk heterojunction polymer solar cells

Svetlana S. Van Bavel, Erwan Sourty, Gijsbertus De With, Joachim Loos

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

Abstract

Currently, one of the most efficient PSCs is the system based on regioregular poly(3-hexylthiophene) (P3HT) as the electron donor and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor material. An essential step to achieve high efficiency is to subject P3HT/PCBM solar cells to an annealing treatment, either at elevated temperature or during slow solvent evaporation (so-called solvent assisted annealing). We have studied the effect of solvent annealing with the assistance of TEM 3D tomography. We have revealed that the morphological changes in a P3HT/PCBM system after thermal or solvent assisted annealing result thus in improved photon absorption, better exciton dissociation, and more efficient and balanced transport of free charges to the electrodes, and are reflected in higher values of fill factor and short-circuit current and hence better overall efficiency of corresponding solar cell devices.

Original languageEnglish
Title of host publicationAmerican Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers
Publication statusPublished - 1 Dec 2009
Event237th National Meeting and Exposition of the American Chemical Society, ACS 2009 - Salt Lake City, UT, United States
Duration: 22 Mar 200926 Mar 2009

Conference

Conference237th National Meeting and Exposition of the American Chemical Society, ACS 2009
CountryUnited States
CitySalt Lake City, UT
Period22/03/0926/03/09

Fingerprint

Butyric acid
Heterojunctions
Annealing
Esters
Butyric Acid
Solar cells
Fullerenes
Electrons
Excitons
Short circuit currents
Tomography
Evaporation
Photons
Transmission electron microscopy
Derivatives
Electrodes
Polymer solar cells
poly(3-hexylthiophene)
Temperature

Cite this

Van Bavel, S. S., Sourty, E., De With, G., & Loos, J. (2009). 3-D Nanoscale organization of bulk heterojunction polymer solar cells. In American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers
Van Bavel, Svetlana S. ; Sourty, Erwan ; De With, Gijsbertus ; Loos, Joachim. / 3-D Nanoscale organization of bulk heterojunction polymer solar cells. American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers. 2009.
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abstract = "Currently, one of the most efficient PSCs is the system based on regioregular poly(3-hexylthiophene) (P3HT) as the electron donor and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor material. An essential step to achieve high efficiency is to subject P3HT/PCBM solar cells to an annealing treatment, either at elevated temperature or during slow solvent evaporation (so-called solvent assisted annealing). We have studied the effect of solvent annealing with the assistance of TEM 3D tomography. We have revealed that the morphological changes in a P3HT/PCBM system after thermal or solvent assisted annealing result thus in improved photon absorption, better exciton dissociation, and more efficient and balanced transport of free charges to the electrodes, and are reflected in higher values of fill factor and short-circuit current and hence better overall efficiency of corresponding solar cell devices.",
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Van Bavel, SS, Sourty, E, De With, G & Loos, J 2009, 3-D Nanoscale organization of bulk heterojunction polymer solar cells. in American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers. 237th National Meeting and Exposition of the American Chemical Society, ACS 2009, Salt Lake City, UT, United States, 22/03/09.

3-D Nanoscale organization of bulk heterojunction polymer solar cells. / Van Bavel, Svetlana S.; Sourty, Erwan; De With, Gijsbertus; Loos, Joachim.

American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers. 2009.

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

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T1 - 3-D Nanoscale organization of bulk heterojunction polymer solar cells

AU - Van Bavel, Svetlana S.

AU - Sourty, Erwan

AU - De With, Gijsbertus

AU - Loos, Joachim

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N2 - Currently, one of the most efficient PSCs is the system based on regioregular poly(3-hexylthiophene) (P3HT) as the electron donor and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor material. An essential step to achieve high efficiency is to subject P3HT/PCBM solar cells to an annealing treatment, either at elevated temperature or during slow solvent evaporation (so-called solvent assisted annealing). We have studied the effect of solvent annealing with the assistance of TEM 3D tomography. We have revealed that the morphological changes in a P3HT/PCBM system after thermal or solvent assisted annealing result thus in improved photon absorption, better exciton dissociation, and more efficient and balanced transport of free charges to the electrodes, and are reflected in higher values of fill factor and short-circuit current and hence better overall efficiency of corresponding solar cell devices.

AB - Currently, one of the most efficient PSCs is the system based on regioregular poly(3-hexylthiophene) (P3HT) as the electron donor and the fullerene derivative [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor material. An essential step to achieve high efficiency is to subject P3HT/PCBM solar cells to an annealing treatment, either at elevated temperature or during slow solvent evaporation (so-called solvent assisted annealing). We have studied the effect of solvent annealing with the assistance of TEM 3D tomography. We have revealed that the morphological changes in a P3HT/PCBM system after thermal or solvent assisted annealing result thus in improved photon absorption, better exciton dissociation, and more efficient and balanced transport of free charges to the electrodes, and are reflected in higher values of fill factor and short-circuit current and hence better overall efficiency of corresponding solar cell devices.

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Van Bavel SS, Sourty E, De With G, Loos J. 3-D Nanoscale organization of bulk heterojunction polymer solar cells. In American Chemical Society - 237th National Meeting and Exposition, ACS 2009, Abstracts of Scientific Papers. 2009