1H and 13C NMR spectral data for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3

L.J.M. Ven, van de; J.W. Haan, de

doi:10.1016/0022-2364(75)90025-6

1H and 13C NMR spectral data for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3

L.J.M. Ven, van de, J.W. Haan, de

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Abstract

1H and 13C NMR spectral data have been obtained for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3, using selective decoupling of proton lines and matching of calculated and experimentally observed spectra. The high-field olefinic proton signals in spiro[4.4]nonadiene-1,3 are assigned to the "inner" olefinic protons. The results indicate that comparable 1H¿1H and 1H¿13C coupling constants in the cyclopentadiene parts of both molecules are similar. This indicates similar bond localizations as well

Original language	English
Pages (from-to)	31-36
Journal	Journal of Magnetic Resonance
Volume	19
Issue number	1
DOIs	https://doi.org/10.1016/0022-2364(75)90025-6
Publication status	Published - 1975

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title = "1H and 13C NMR spectral data for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3",

abstract = "1H and 13C NMR spectral data have been obtained for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3, using selective decoupling of proton lines and matching of calculated and experimentally observed spectra. The high-field olefinic proton signals in spiro[4.4]nonadiene-1,3 are assigned to the {"}inner{"} olefinic protons. The results indicate that comparable 1H¿1H and 1H¿13C coupling constants in the cyclopentadiene parts of both molecules are similar. This indicates similar bond localizations as well",

author = "{Ven, van de}, L.J.M. and {Haan, de}, J.W.",

year = "1975",

doi = "10.1016/0022-2364(75)90025-6",

language = "English",

volume = "19",

pages = "31--36",

journal = "Journal of Magnetic Resonance",

issn = "1090-7807",

publisher = "Academic Press Inc.",

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T1 - 1H and 13C NMR spectral data for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3

AU - Ven, van de, L.J.M.

AU - Haan, de, J.W.

PY - 1975

Y1 - 1975

N2 - 1H and 13C NMR spectral data have been obtained for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3, using selective decoupling of proton lines and matching of calculated and experimentally observed spectra. The high-field olefinic proton signals in spiro[4.4]nonadiene-1,3 are assigned to the "inner" olefinic protons. The results indicate that comparable 1H¿1H and 1H¿13C coupling constants in the cyclopentadiene parts of both molecules are similar. This indicates similar bond localizations as well

AB - 1H and 13C NMR spectral data have been obtained for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3, using selective decoupling of proton lines and matching of calculated and experimentally observed spectra. The high-field olefinic proton signals in spiro[4.4]nonadiene-1,3 are assigned to the "inner" olefinic protons. The results indicate that comparable 1H¿1H and 1H¿13C coupling constants in the cyclopentadiene parts of both molecules are similar. This indicates similar bond localizations as well

U2 - 10.1016/0022-2364(75)90025-6

DO - 10.1016/0022-2364(75)90025-6

M3 - Article

SN - 1090-7807

VL - 19

SP - 31

EP - 36

JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

IS - 1

ER -

1H and 13C NMR spectral data for spiro[2.4]heptadiene-4,6 and spiro[4.4]nonadiene-1,3

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