Abstract
Furfural (FF) and 5-hydroxymethylfurfural (HMF) are intermediates for many products, such as monomers for bioplastics, and can be obtained from various renewable resources. The isolation of these sugar-derived molecules from aqueous solutions is one of the main challenges in biorefinery processes. In the work described in this paper, the separation of FF and HMF from aqueous phases is carried out with hydrophobic deep eutectic solvents (DESs) as new extracting agents. Distribution coefficients of FF and HMF in 10 different hydrophobic DES + water systems have been measured and compared to that of the benchmark extracting agent (toluene). The dependence of the distribution coefficients on the presence of sugars in the system has also been investigated. The hydrophobic DESs were found to selectively extract FF and HMF from aqueous solutions without any co-extraction or precipitation of sugars. Finally, the distribution coefficients have been successfully predicted with PC-SAFT (perturbed-chain statistical associating fluid theory) without the need to fit any parameter to the measured distribution coefficients.
| Language | English |
|---|---|
| Pages | 4240-4247 |
| Number of pages | 8 |
| Journal | Industrial and Engineering Chemistry Research |
| Volume | 58 |
| Issue number | 10 |
| DOIs | |
| State | Published - 13 Mar 2019 |
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110th Anniversary: Distribution coefficients of furfural and 5-hydroxymethylfurfural in hydrophobic deep eutectic solvent + water systems: experiments and perturbed-chain statistical associating fluid theory predictions. / Dietz, Carin H.J.T.; Gallucci, Fausto; van Sint Annaland, Martin; Held, Christoph (Corresponding author); Kroon, Maaike C. (Corresponding author).
In: Industrial and Engineering Chemistry Research, Vol. 58, No. 10, 13.03.2019, p. 4240-4247.Research output: Contribution to journal › Article › Academic › peer-review
TY - JOUR
T1 - 110th Anniversary: Distribution coefficients of furfural and 5-hydroxymethylfurfural in hydrophobic deep eutectic solvent + water systems: experiments and perturbed-chain statistical associating fluid theory predictions
AU - Dietz,Carin H.J.T.
AU - Gallucci,Fausto
AU - van Sint Annaland,Martin
AU - Held,Christoph
AU - Kroon,Maaike C.
PY - 2019/3/13
Y1 - 2019/3/13
N2 - Furfural (FF) and 5-hydroxymethylfurfural (HMF) are intermediates for many products, such as monomers for bioplastics, and can be obtained from various renewable resources. The isolation of these sugar-derived molecules from aqueous solutions is one of the main challenges in biorefinery processes. In the work described in this paper, the separation of FF and HMF from aqueous phases is carried out with hydrophobic deep eutectic solvents (DESs) as new extracting agents. Distribution coefficients of FF and HMF in 10 different hydrophobic DES + water systems have been measured and compared to that of the benchmark extracting agent (toluene). The dependence of the distribution coefficients on the presence of sugars in the system has also been investigated. The hydrophobic DESs were found to selectively extract FF and HMF from aqueous solutions without any co-extraction or precipitation of sugars. Finally, the distribution coefficients have been successfully predicted with PC-SAFT (perturbed-chain statistical associating fluid theory) without the need to fit any parameter to the measured distribution coefficients.
AB - Furfural (FF) and 5-hydroxymethylfurfural (HMF) are intermediates for many products, such as monomers for bioplastics, and can be obtained from various renewable resources. The isolation of these sugar-derived molecules from aqueous solutions is one of the main challenges in biorefinery processes. In the work described in this paper, the separation of FF and HMF from aqueous phases is carried out with hydrophobic deep eutectic solvents (DESs) as new extracting agents. Distribution coefficients of FF and HMF in 10 different hydrophobic DES + water systems have been measured and compared to that of the benchmark extracting agent (toluene). The dependence of the distribution coefficients on the presence of sugars in the system has also been investigated. The hydrophobic DESs were found to selectively extract FF and HMF from aqueous solutions without any co-extraction or precipitation of sugars. Finally, the distribution coefficients have been successfully predicted with PC-SAFT (perturbed-chain statistical associating fluid theory) without the need to fit any parameter to the measured distribution coefficients.
UR - http://www.scopus.com/inward/record.url?scp=85062912108&partnerID=8YFLogxK
U2 - 10.1021/acs.iecr.8b06234
DO - 10.1021/acs.iecr.8b06234
M3 - Article
VL - 58
SP - 4240
EP - 4247
JO - Industrial and Engineering Chemistry Research
T2 - Industrial and Engineering Chemistry Research
JF - Industrial and Engineering Chemistry Research
SN - 0888-5885
IS - 10
ER -