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ZnO is a material of high technological interest. Mineralizing ZnO in confinement should allow for enhanced properties, to achieve this it is essential to understand the underlaying formation mechanism.

Research profile

In nature hierarchical organic-inorganic composites show highly tailored properties. This is not due to their chemical compositions but thanks to precise control over both shape and structure. One example is the mineralization of collagen with calcium phosphate in bone which results in remarkable mechanical properties. Its highly-defined pores make materials like collagen a template of interest for many more inorganic phases than only calcium phosphate. One of these inorganic phases is zinc oxide (ZnO). ZnO is a metal oxide with a range of electro and opto-electronic properties. By mineralizing ZnO in the confinement enhanced and selective control over these properties should be achievable.

Academic background

Mark van Rijt is a PhD student at the Laboratory of Physical Chemistry. He received his bachelor's degree at Fontys University of Applied Science writing his thesis in the group of prof. Steven P. Armes, at the University of Sheffield, on Well-defined Organic Vesicular Templates for Hybrid Core-shell Nanoparticles (2014). He obtained his master's degree at Eindhoven University of Technology (met grote waardering) writing his thesis in the Materials and Interface Chemistry group (SMG) of Prof. Nico A. J. M. Sommerdijk on the Self-Assembly of Defined Block Copolypeptides (2017).


Currently he is working with Prof. Bert de With towards understanding and controlling the mechanism of zinc oxide formation.

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Research Output

  • 43 Citations
  • 5 Article
  • 2 Conference contribution

Nanohybrid materials with tunable birefringence via cation exchange in polymer films

Oosterlaken, B., Xu, Y., van Rijt, M., Pilz Da Cunha, M., Timmermans, G., Debije, M., Friedrich, H., Schenning, A. & Sommerdijk, N., 1 Feb 2020, In : Advanced Functional Materials. 30, 6, 6 p., 1907456.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
  • 1 Citation (Scopus)
    17 Downloads (Pure)

    One Peptide for Them All: Gold Nanoparticles of Different Sizes Are Stabilized by a Common Peptide Amphiphile

    Egorova, E. A., van Rijt, M. M. J., Sommerdijk, N., Gooris, G. S., Bouwstra, J. A., Boyle, A. L. & Kros, A., 26 May 2020, In : ACS Nano. 14, 5, p. 5874-5886 13 p.

    Research output: Contribution to journalArticleAcademicpeer-review

    Open Access
  • Designing stable, hierarchical peptide fibers from block co-polypeptide sequences

    van Rijt, M., Ciaffoni, A., Ianiro, A., Moradi, M., Boyle, A. L., Kros, A., Friedrich, H., Sommerdijk, N. & Patterson, J. P., 7 Aug 2019, In : Chemical Science. 10, 39, p. 9001-9008 8 p.

    Research output: Contribution to journalArticleAcademicpeer-review

    Open Access
  • 2 Citations (Scopus)
    16 Downloads (Pure)

    Liquid–liquid phase separation during amphiphilic self-assembly

    Ianiro, A., Wu, H., van Rijt, M. M. J., Vena, M. P., Keizer, A. D. A., Esteves, A. C. C., Tuinier, R., Friedrich, H., Sommerdijk, N. A. J. M. & Patterson, J. P., 1 Apr 2019, In : Nature Chemistry. 11, 4, p. 320-328 9 p.

    Research output: Contribution to journalArticleAcademicpeer-review

    Open Access
  • 29 Citations (Scopus)
    182 Downloads (Pure)

    A roadmap for poly(ethylene oxide)-block-poly-ε-caprolactone self-assembly in water : prediction, synthesis, and characterization and characterization

    Ianiro, A., Patterson, J. P., Gonzalez Garcia, A., van Rijt, M. M. J., Hendrix, M. M. R. M., Sommerdijk, N. A. J. M., Voets, I. K., de Carvalho Esteves, A. C. & Tuinier, R., 15 Feb 2018, In : Journal of Polymer Science, Part B: Polymer Physics. 56, 4, p. 330-339 10 p.

    Research output: Contribution to journalArticleAcademicpeer-review

    Open Access
  • 11 Citations (Scopus)
    66 Downloads (Pure)

    Student theses

    Self-assembly of defined block copolypeptides

    Author: van Rijt, M., 22 Feb 2017

    Supervisor: Sommerdijk, N. (Supervisor 1) & Patterson, J. (Supervisor 2)

    Student thesis: Master