Personal profile
Quote
"Realizing the clean energy transition requires the development of advanced and competitive catalytic technology, to increase the share of renewable energy in the production of fuels and chemicals."
Research profile
The research of Emiel Hensen focuses on the fundamental aspects of catalyzed reactions relevant to clean and sustainable processes for the production of fuels and chemicals. The aim hereby is to identify active sites and understand reaction mechanisms. The working approach is to combine
- advanced operando characterization methods - X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, vibrational spectroscopy applied to well-defined catalyst model systems;
- theoretical modeling (density functional theory, microkinetics); and
- performance testing (kinetics, high-throughput methods, transient techniques),
to guide the design and synthesis of nanoscopically organized and well-defined chemically functionalized catalytic solid materials. The materials explored include primarily highly structured porous materials containing reactive centers such as protons, metal ions and metal, metal oxide and metal sulfides clusters.
Applications are directed towards the improvement of current industrial chemical processes and novel processes based on renewable feedstock such as biomass. Catalytic target reactions are methane activation, the Fischer-Tropsch reaction, conversion of biogenic molecules such as sugars and lignin, and metal-support cooperativity in selective oxidation. In these areas of research Hensen has made many innovative, internationally recognized scientific contributions. Hensen has pioneered the fields of Lewis-acid catalysed conversion of sugars, catalytic upgrading of lignin, synthesis of hierarchical zeolites, and microkinetics simulations of heterogeneous reactions.
Academic background
Emiel Hensen received his master degree in chemical engineering and chemistry from Eindhoven University of Technology (TU/e) in 1994. In 2000 he obtained his PhD from the same university in the field of molecular heterogeneous catalysis under the supervision of professors Rutger van Santen and Rob van Veen. He then took up an assistant professor position with Prof. Berend Smit at University of Amsterdam. In 2001 he returned to TU/e as an assistant professor and in 2008 he was promoted to associate professor. From 2006-2008 he was a visiting research scientist at the Shell Research and Technology Center Amsterdam (The Netherlands). Since July 2009 Hensen is full professor of inorganic materials chemistry at TU/e. He was a visiting professor at Katholieke Universiteit Leuven (Belgium) from 2001 until 2016 and a visiting professor at Hokkaido University (Japan) in 2016. Hensen was appointed dean of the TU/e department of Chemical Engineering and Chemistry in 2016. He is member of the Dutch Advanced Research Center Chemical Building Blocks Consortium and chairman of the Netherlands Institute for Catalysis Research (NIOK).
Affiliated with
- Netherlands Research School for Catalysis (NIOK, chairman)
- European Research Institute of Catalysis (ERIC, board member)
- Gravitation program Multiscale Catalytic Energy Conversoin (MCEC, MT member)
Expertise related to UN Sustainable Development Goals
In 2015, UN member states agreed to 17 global Sustainable Development Goals (SDGs) to end poverty, protect the planet and ensure prosperity for all. This person’s work contributes towards the following SDG(s):
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SDG 3 Good Health and Well-being
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SDG 7 Affordable and Clean Energy
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SDG 12 Responsible Consumption and Production
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SDG 13 Climate Action
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SDG 14 Life Below Water
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Collaborations and top research areas from the last five years
Projects
- 3 Finished
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Renewable jet fuel range hydrocarbons from biomass residues derived lignin - TIND221009
Boot, M. D. (Project Manager), Hensen, E. J. M. (Project member) & Yang, H. (Project member)
1/03/22 → 1/07/25
Project: Third tier
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Hydrogenation processing for Goldilocks resulting in biofuels - TIND221005
Boot, M. D. (Project Manager), Zuidema, N. (Project member), Verhoeven, M. W. G. M. (Project member) & Hensen, E. J. M. (Project member)
1/01/22 → 31/03/26
Project: Third tier
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Interface Catalysis for Advanced Sustainable Chemistry 2020.021
Hensen, E. J. M. (Project Manager), Muravev, V. (Project member), Jestl, V. (Project member) & Broens, D. G. J. (Project member)
1/01/21 → 10/12/24
Project: Third tier
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Interface dynamics of Pd–CeO2 single-atom catalysts during CO oxidation
Muravev, V., Spezzati, G., Su, Y. Q., Parastaev, A., Chiang, F. K., Longo, A., Escudero, C., Kosinov, N. & Hensen, E. J. M. (Corresponding author), Jun 2021, In: Nature Catalysis. 4, 6, p. 469-478 10 p.Research output: Contribution to journal › Article › Academic › peer-review
Open AccessFile502 Link opens in a new tab Citations (Scopus)1725 Downloads (Pure) -
Boosting CO2 hydrogenation via size-dependent metal-support interactions in cobalt-ceria-based catalysts
Parastaev, A., Muravev, V., Huertas Osta, E., van Hoof, A. J. F., Kimpel, T., Kosinov, N. A. & Hensen, E. J. M. (Corresponding author), 1 Jun 2020, In: Nature Catalysis. 3, 6, p. 526-533 8 p.Research output: Contribution to journal › Article › Academic › peer-review
Open AccessFile546 Link opens in a new tab Citations (Scopus)918 Downloads (Pure) -
Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
Tian, X. (Corresponding author), Zhao, X., Su, Y. Q., Wang, L., Wang, H., Dang, D., Chi, B., Liu, H., Hensen, E. J. M., Lou, X. W. (Corresponding author) & Xia, B. Y. (Corresponding author), 15 Nov 2019, In: Science. 366, 6467, p. 850-856 7 p.Research output: Contribution to journal › Article › Academic › peer-review
1388 Link opens in a new tab Citations (Scopus)8 Downloads (Pure) -
Highly efficient and robust Au/MgCuCr2O4 catalyst for gas-phase oxidation of ethanol to acetaldehyde
Liu, P. & Hensen, E. J. M., 2013, In: Journal of the American Chemical Society. 135, 38, p. 14032-14035 4 p.Research output: Contribution to journal › Article › Academic › peer-review
555 Link opens in a new tab Citations (Scopus)3 Downloads (Pure) -
Confined carbon mediating dehydroaromatization of methane over Mo/ZSM-5
Kosinov, N., Wijpkema, A. S. G., Uslamin, E., Rohling, R., Coumans, F. J. A. G., Mezari, B., Parastaev, A., Poryvaev, A. S., Fedin, M. V., Pidko, E. A. & Hensen, E. J. M., 22 Jan 2018, In: Angewandte Chemie. 130, 4, p. 1028–1032Research output: Contribution to journal › Article › Academic › peer-review
Open AccessFile515 Downloads (Pure)
Datasets
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Electronic structure and interface energetics of CuBi2O4 photoelectrodes - data
Oropeza, F. E. (Creator), Dzade, N. Y. (Creator), Pons Marti, A. (Contributor), Yang, Z. (Creator), Zhang, K. H. L. (Creator), de Leeuw, N. H. (Creator), Hensen, E. J. M. (Creator) & Hofmann, J. P. (Creator), Cardiff University, 30 Jun 2020
DOI: 10.17035/d.2020.0117701577
Dataset
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Supplementary data for the paper: Impact of small promoter amounts on coke structure in dry reforming of methane over Ni/ ZrO2
Franz, R. (Creator), Kühlewind, T. (Creator), Shterk, G. (Creator), Abou-Hamad, E. (Creator), Parastaev, A. (Creator), Uslamin, E. (Creator), Hensen, E. J. M. (Creator), Kapteijn, F. (Creator), Gascon, J. (Creator) & Pidko, E. A. (Creator), 4TU.Centre for Research Data, 10 Jun 2020
DOI: 10.4121/uuid:44f4246c-734f-45ce-9ced-c6ee4c614dd2
Dataset
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Density of states and Crystal Orbital Hamilton Population Analysis of CO adsorbed on Co
Krosschell, R. (Creator), Hensen, E. (Creator) & Filot, I. (Creator), Zenodo, 19 Dec 2023
DOI: 10.5281/zenodo.10405016, https://zenodo.org10405016 and one more link, https://zenodo.org/records/10885762 (show fewer)
Dataset
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ifilot/microkinetic-datasets-methanation-fts: Fix error in description
Zijlstra, B. (Creator), Klumpers, B. (Creator), Hensen, E. J. M. (Creator) & Filot, I. A. W. (Creator), Zenodo, 12 Aug 2023
DOI: 10.5281/zenodo.8241527, https://zenodo.org/records/8241527
Dataset
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CCDC 1849321: Experimental Crystal Structure Determination
Filonenko, G. A. (Contributor), Lugger, J. (Contributor), Liu, C. (Contributor), van Heeswijk, E. P. A. (Contributor), Hendrix, M. M. R. M. (Contributor), Weber, M. (Contributor), Müller, C. (Contributor), Hensen, E. J. M. (Contributor), Sijbesma, R. P. (Contributor) & Pidko, E. A. (Contributor), Cambridge Crystallographic Data Centre, 14 Jun 2018
DOI: 10.5517/ccdc.csd.cc202cj0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc202cj0&sid=DataCite
Dataset
Prizes
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Top Grant: Nanoparticles Caught in the Catalytic Act by In-situ Diffraction:Towards Understanding Structure Sensitivity
Hensen, E. J. M. (Recipient), 2013
Prize: NWO › Other › Scientific
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NWO Vici Award Laureate Technologiestichting STW : Optimal nanoparticles for sustainable catalysis
Hensen, E. (Recipient), 2013
Prize: NWO › Vici › Scientific
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Vidi Laureate: Bottom-up design van poreuze katalysatoren
Hensen, E. J. M. (Recipient), 2007
Prize: NWO › Vidi › Scientific
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Veni beurs: ‘Towards a new energy-efficient catalytic process for the production of lower olefins from paraffin feedstock’
Hensen, E. J. M. (Recipient), 2002
Prize: NWO › Other › Scientific
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Casimir Laureate: Innovaties in hydrocracking processen voor het opwerken van zware aardoliefracties naar schone brandstoffen
Hensen, E. J. M. (Recipient), 2006
Prize: NWO › Other › Scientific
File
Courses
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Capita selecta
Course
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Catalysis science and technology
Filot, I. A. W., Hensen, E. J. M. & van Etten, M. P. C. 1/09/14 → 31/08/26
Course
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Design project
Manito Pereira Rovers, A., Rebrov, E., Kuipers, J. A. M., van Sint Annaland, M., van der Schaaf, J., Hensen, E. J. M., Gallucci, F., Kosinov, N. A., Finotello, G., Peters, E. A. J. F. & Forner Cuenca, A. 1/09/19 → 31/08/26
Course
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Press/Media
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Eindhoven University of Technology Reports Findings in Nanoparticles (Structure Sensitivity of CO2 Hydrogenation on Ni Revisited)
Hensen, E. J. M., Kosinov, N. A., Simons, J. F. M. & Muravev, V.
21/09/23
1 item of Media coverage
Press/Media: Expert Comment
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New Findings from Eindhoven University of Technology Describe Advances in Nanoparticles (Unraveling the Role of Metal-support Interactions On the Structure Sensitivity of Fischer-tropsch Synthesis)
Filot, I. A. W. & Hensen, E. J. M.
13/09/23
1 item of Media coverage
Press/Media: Expert Comment
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Eindhoven University of Technology Reports Findings in Science (Pt/CeO2 as Catalyst for Nonoxidative Coupling of Methane: Oxidative Regeneration)
Hensen, E. J. M., Kosinov, N. A., Simons, J. F. M., Muravev, V., Liutkova, A., Zhang, H. & Liu, L.
7/08/23
1 item of Media coverage
Press/Media: Expert Comment
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Eindhoven University of Technology Reports Findings in Science (Role of Strontium Cations in ZSM-5 Zeolite in the Methanol-to-Hydrocarbons Reaction)
Hensen, E. J. M., Kosinov, N. A., Mezari, B., Liutkova, A., Heinrichs, J. M. J. J. & Drozhzhin, V.
21/07/23
1 item of Media coverage
Press/Media: Expert Comment
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Eindhoven University of Technology Reports Findings in Science (Revealing Active Sites and Reaction Pathways in Methane Non-Oxidative Coupling over Iron-Containing Zeolites)
Hensen, E. J. M., Kosinov, N. A. & Zhang, H.
14/07/23
1 item of Media coverage
Press/Media: Expert Comment
Thesis
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A kinetic study of periodic trends and promotional behaviour in hydrotreating catalysis
Hensen, E. (Author), van Santen, R. A. (Supervisor 1), 31 Dec 1994Student thesis: Master