Total Research Program Chemical and Process Technology

Research Output 1966 2020

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Article
2020
1 Citation (Scopus)
6 Downloads (Pure)

A quantum-chemical study of the CO dissociation mechanism on low-index Miller planes of ϴ-Fe 3 C

Broos, R. J. P., Klumpers, B., Zijlstra, B., Filot, I. A. W. & Hensen, E. J. M., 15 Feb 2020, In : Catalysis Today. 342, p. 152-160 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
Chemical activation
Carbides
Fischer-Tropsch synthesis
Cobalt

Aromatization of ethylene over zeolite-based catalysts

Uslamin, E. A., Saito, H., Kosinov, N. A., Pidko, E. A., Sekine, Y. & Hensen, E. J. M., 2020, (Accepted/In press) In : Catalysis Science & Technology.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Aromatization
Zeolites
Ethylene
Catalysts
Aromatic compounds

CFD analysis of a luminescent solar concentrator-based photomicroreactor (LSC-PM) with feedforward control applied to the synthesis of chemicals under fluctuating light intensity

de Oliveira, G. X., Lira, J. O. B., Cambié, D., Noël, T., Riella, H. G., Padoin, N. & Soares, C., 1 Jan 2020, In : Chemical Engineering Research and Design. 153, p. 626-634 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Solar concentrators
Feedforward control
Dynamic analysis
Computational fluid dynamics
Dynamic models
6 Downloads (Pure)

Effect of proximity and support material on deactivation of bifunctional catalysts for the conversion of synthesis gas to olefins and aromatics

Weber, J. L., Krans, N. A., Hofmann, J. P., Hensen, E. J. M., Zecevic, J., de Jongh, P. E. & de Jong, K. P., 15 Feb 2020, In : Catalysis Today. 342, p. 161-166 6 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Synthesis gas
Alkenes
Catalyst supports
Olefins
Catalysts

Electrochemical stability of RuO2(110)/Ru(0001) model electrodes in the oxygen and chlorine evolution reactions

Goryachev, A., Etzi Coller Pascuzzi, M., Carlà, F., Weber, T., Over, H., Hensen, E. J. M. & Hofmann, J. P., 2020, (Accepted/In press) In : Electrochimica Acta. 336, 135713.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
1 Citation (Scopus)
3 Downloads (Pure)

First-principles based microkinetic modeling of transient kinetics of CO hydrogenation on cobalt catalysts

Zijlstra, B., Broos, R., Chen, W., Filot, I. & Hensen, E., 15 Feb 2020, In : Catalysis Today. 342, p. 131-141 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Carbon Monoxide
Cobalt
Hydrogenation
Catalysts
Kinetics

First-principles microkinetics simulations of electrochemical reduction of CO2 over Cu catalysts

Zijlstra, B., Zhang, X., Liu, J-X., Filot, I. A. W., Zhou, Z., Sun, S. & Hensen, E. J. M., 2020, (Accepted/In press) In : Electrochimica Acta.

Research output: Contribution to journalArticleAcademicpeer-review

Improving the physicochemical properties of Y zeolite for catalytic cracking of heavy oil via sequential steam-alkali-acid treatments

Aghaei, E., Karimzadeh, R., Godini, H. R., Gurlo, A. & Gorke, O., 1 Mar 2020, In : Microporous and Mesoporous Materials. 294, 15 p., 109854.

Research output: Contribution to journalArticleAcademicpeer-review

Zeolites
Catalytic cracking
Steam
Alkalies
steam

Increased activity in the oxygen evolution reaction by Fe4+-induced hole states in perovskite La1-xSrxFeO3

Shen, Z., Zhuang, Y., Li, W., Huang, X., Oropeza, F. E., Hensen, E. J. M., Hofmann, J. P., Cui, M., Tadich, A., Qi, D., Cheng, J., Li, J. & Zhang, K. H. L., 2020, (Accepted/In press) In : Journal of Materials Chemistry A.

Research output: Contribution to journalArticleAcademicpeer-review

In situ shell-isolated nanoparticle-enhanced raman spectroscopy of nickel-catalyzed hydrogenation reactions’

Wondergem, C. S., Kromwijk, J. J. G., Slagter, M. M., Vrijburg, W. L., Hensen, E. J. M., Monai, M., Vogt, C. & Weckhuysen, B. M., 2020, (Accepted/In press) In : ChemPhysChem.

Research output: Contribution to journalArticleAcademicpeer-review

Investigation of the active phase in K-promoted MoS2 catalysts for methanethiol synthesis

Yu, M., Kosinov, N. A., van Haandel, L., Kooyman, P. J. & Hensen, E. J. M., 2020, In : ACS Catalysis.

Research output: Contribution to journalArticleAcademicpeer-review

Carbon Monoxide
Catalysts
X ray photoelectron spectroscopy
Productivity
Transmission electron microscopy
1 Downloads (Pure)

Mechanistic role of protonated polar additives in ethanol for selective transformation of biomass-related compounds

Guo, H., Duereh, A., Su, Y-Q., Hensen, E. J. M., Qi, X. & Smith Jr., R. L., 5 May 2020, In : Applied Catalysis. B, Environmental. 264, 9 p., 118509.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
ethanol
Biomass
Ethanol
Dimethyl Sulfoxide
Dehydration
16 Downloads (Pure)

Mn promotion of rutile TiO2-RuO2 anodes for water oxidation in acidic media

Etzi Coller Pascuzzi, M., Goryachev, A., Hofmann, J. P. & Hensen, E. J. M., 1 Feb 2020, In : Applied Catalysis. B, Environmental. 261, 11 p., 118225.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
rutile
Anodes
oxidation
Oxidation
Water

Porous nitrogen-doped carbon/carbon nanocomposite electrodes enable sodium ion capacitors with high capacity and rate capability

Yan, R., Leus, K., Hofmann, J. P., Antonietti, M. & Oschatz, M., Jan 2020, In : Nano Energy. 67, 8 p., 104240.

Research output: Contribution to journalArticleAcademicpeer-review

Energy storage
Nanocomposites
Capacitors
Nitrogen
Carbon

Screening of functional solvent system for automatic aldehyde and ketone separation in aldol reaction: a combined COSMO-RS and experimental approach

Zhang, C., Song, Z., Jin, C., Nijhuis, J., Zhou, T., Noël, T., Gröger, H., Sundmacher, K., van Hest, J. & Hessel, V., 1 Apr 2020, In : Chemical Engineering Journal. 385, 10 p., 123399.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
ketone
aldehyde
Ketones
Aldehydes
Screening

Selective hydrogenation of 5 hydroxymethylfurfural and its acetal with 1,3-propanediol to 2,5-bis(hydroxymethyl)furan using supported rhenium-promoted nickel catalysts in water

Wiesfeld, J. J., Kim, M., Nakajima, K. & Hensen, E. J. M., 13 Jan 2020, (Accepted/In press) In : Green Chemistry.

Research output: Contribution to journalArticleAcademicpeer-review

The butoxylation of dodecylamine: reaction mechanism and kinetics

Müller, P., Krösschell, R. D. E., Winkenwerder, W. & van der Schaaf, J., 15 Feb 2020, In : Chemical Engineering Journal. 382, 9 p., 122939.

Research output: Contribution to journalArticleAcademicpeer-review

Amines
kinetics
Kinetics
Hydroxyl Radical
Ethylene Oxide

Three-dimensional hierarchical CuxS-based evaporator for high-efficiency multifunctional solar distillation

Huang, W., Su, P., Cao, Y., Li, C., Chen, D., Tian, X., Su, Y., Qiao, B., Tu, J. & Wang, X., Mar 2020, In : Nano Energy. 69, 104465.

Research output: Contribution to journalArticleAcademicpeer-review

Evaporators
Distillation
Water
Foams
Evaporation
2019
6 Citations (Scopus)
1 Downloads (Pure)
Signal filtering and prediction
Furaldehyde
Furfural
Eutectics
Sugars
4 Citations (Scopus)
110 Downloads (Pure)

3D printed versus spherical adsorbents for gas sweetening

Middelkoop, V., Coenen, K., Schalck, J., van Sint Annaland, M. & Gallucci, F., 1 Feb 2019, In : Chemical Engineering Journal. 357, p. 309-319 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Adsorbents
Gases
adsorption
Adsorption
gas
24 Downloads (Pure)
Open Access
File
Phase transitions
Direct numerical simulation
Bubbles (in fluids)
Gravitation
Temperature distribution
9 Downloads (Pure)

Activation of co–mo–S hydrodesulfurization catalysts under refinery conditions: a combined SAXS/XAS study

van Haandel, L., Longo, A., Bras, W., Hensen, E. J. M. & Weber, T., 18 Oct 2019, In : ChemCatChem. 11, 20, p. 5013-5017 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Hydrodesulfurization
Chemical activation
activation
catalysts
Catalysts
1 Citation (Scopus)

Activity modelling of the solid-liquid equilibrium of deep eutectic solvents

Kollau, L. J. B. M., Vis, M., van den Bruinhorst, A., de With, G. & Tuinier, R., 1 Aug 2019, In : Pure and Applied Chemistry. 91, 8, p. 1341–1349 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Eutectics
Liquids
Melting point
Binary mixtures
Activity coefficients
2 Citations (Scopus)
16 Downloads (Pure)

A facile direct route to N-(un)substituted lactams by cycloamination of oxocarboxylic acids without external hydrogen

Li, H., Wu, H., Zhang, H., Su, Y., Song, Y. & Hensen, E., 22 Aug 2019, In : ChemSusChem. 12, 16, p. 3778-3784 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Lactams
Hydrogen
hydrogen
formic acid
Acids

A multi-perspectives analysis of methane oxidative coupling process based on miniplant-scale experimental data

Godini, H. R., Azadi, M., Penteado, A., Khadivi, M., Wozny, G. & Repke, J. U., 1 Nov 2019, In : Chemical Engineering Research and Design. 151, p. 56-69 14 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methane
Ethylene
Economics
Natural gas conditioning
Ethane
26 Downloads (Pure)

An asymmetric organocatalytic aldol reaction of a hydrophobic aldehyde in aqueous medium running in flow mode

Schober, L., Ratnam, S., Yamashita, Y., Adebar, N., Pieper, M., Berkessel, A., Hessel, V. & Gröger, H., Mar 2019, In : Synthesis. 51, 5, p. 1178-1184 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Enantioselectivity
Propanol
Aldehydes
2-Propanol
Substrates

An Fe stabilized metallic phase of NiS2 for the highly efficient oxygen evolution reaction

Ding, X., Li, W., Kuang, H., Qu, M., Cui, M., Zhao, C., Qi, D. C., Oropeza, F. E. & Zhang, K. H. L., 28 Dec 2019, In : Nanoscale. 11, 48, p. 23217-23225 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Oxygen
Catalysts
Doping (additives)
Reactive Oxygen Species
Hydroxides
12 Downloads (Pure)
Open Access
File
Cyclohexanols
Gold
Gases
Nanoparticles
Oxidation
17 Citations (Scopus)
75 Downloads (Pure)

A search for natural hydrophobic deep eutectic solvents based on natural components

van Osch, D. J. G. P., Dietz, C. H. J. T., van Spronsen, J., Kroon, M. C., Gallucci, F., van Sint Annaland, M. & Tuinier, R., 4 Feb 2019, In : ACS Sustainable Chemistry & Engineering. 7, 3, p. 2933-2942 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Eutectics
Thymol
Menthol
Riboflavin
Water
3 Citations (Scopus)
4 Downloads (Pure)

A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation

Vollmer, I., Kosinov, N., Szécsényi, Á., Li, G., Yarulina, I., Abou-Hamad, E., Gurinov, A., Ould-Chikh, S., Aguilar-Tapia, A., Hazemann, J. L., Pidko, E., Hensen, E., Kapteijn, F. & Gascon, J., 1 Feb 2019, In : Journal of Catalysis. 370, p. 321-331 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methane
Carbon Monoxide
Benzene
Zeolites
Chemical activation

Assessment of the location of Pt nanoparticles in Pt/zeolite Y/γ‑Al2O3 composite catalysts

Oenema, J., Hofmann, J. P., Hensen, E., Zecevic, J. & de Jong, K. P., 2 Oct 2019, (Accepted/In press) In : ChemCatChem.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Zeolites
Nanoparticles
catalysts
nanoparticles
Catalysts

A theoretical study of the reverse water-gas shift reaction on Ni(111) and Ni(311) surfaces

Zhang, M., Zijlstra, B., Filot, I., Li, F., Wang, H., Li, J. & Hensen, E., 2019, (Accepted/In press) In : Canadian Journal of Chemical Engineering.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Water gas shift
Carbon Monoxide
Chemical activation
Water
Redox reactions
4 Downloads (Pure)

A versatile mono-quaternary ammonium salt as a mesoporogen for the synthesis of hierarchical zeolites

Bolshakov, A., van Hoof, A., Mezari, B., Kosinov, N. & Hensen, E., 7 Dec 2019, In : Catalysis Science & Technology. 9, 23, p. 6737-6748 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Zeolites
Ammonium Compounds
Salts
Butenes
1-Butanol
41 Downloads (Pure)

Bio-based chemicals: Selective aerobic oxidation of tetrahydrofuran-2,5-dimethanol to tetrahydrofuran-2,5-dicarboxylic acid using hydrotalcite-supported gold catalysts

Yuan, Q., Hiemstra, K., Meinds, T. G., Chaabane, I., Tang, Z., Rohrbach, L., Vrijburg, W., Verhoeven, T., Hensen, E. J. M., van der Veer, S., Pescarmona, P. P., Heeres, H. J. & Deuss, P. J., 4 Mar 2019, In : ACS Sustainable Chemistry & Engineering. 7, 5, p. 4647-4656 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
hydrotalcite
Dicarboxylic Acids
Gold
gold
catalyst
1 Citation (Scopus)

Boosting CO2 methanation activity on Ru/TiO2 catalysts by exposing (001) facets of anatase TiO2

Chai, S., Men, Y., Wang, J., Liu, S., Song, Q., An, W. & Kolb, G., 1 Oct 2019, In : Journal of CO2 Utilization. 33, p. 242-252 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methanation
anatase
physicochemical property
Titanium dioxide
catalyst
1 Citation (Scopus)
8 Downloads (Pure)

Catalytic conversion of lignin in woody biomass into phenolic monomers in methanol/water mixtures without external hydrogen

Ouyang, X., Huang, X., Zhu, J., Boot, M. & Hensen, E., 19 Aug 2019, In : ACS Sustainable Chemistry & Engineering. 7, 16, p. 13764-13773 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Lignin
lignin
Methanol
methanol
Hydrogen
3 Citations (Scopus)
58 Downloads (Pure)

Cellulose conversion to ethylene glycol by tungsten oxide-based catalysts

Wiesfeld, J., Peršolja, P., Rollier, F. A., Elemans - Mehring, A. & Hensen, E., 1 Aug 2019, In : Molecular Catalysis. 473, 110400.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
tungsten oxides
Ethylene Glycol
Ethylene glycol
cellulose
Cellulose
1 Citation (Scopus)
9 Downloads (Pure)

Ceria-Zirconia encapsulated Ni nanoparticles for CO2 methanation

Vrijburg, W., van Helden, J. W. A., Parastaev, A., Groeneveld, E., Pidko, E. & Hensen, E., 12 Aug 2019, In : Catalysis Science & Technology. 9, 18, p. 5001-5010 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Methanation
Cerium compounds
Zirconia
Nanoparticles
Catalysts
1 Citation (Scopus)
15 Downloads (Pure)

Characterization and effect of Ag(0) vs. Ag(I) species and their localized plasmon resonance on photochemically inactive TiO 2

Handoko, C. T., Moustakas, N. G., Peppel, T., Springer, A., Oropeza, F. E., Huda, A., Bustan, M. D., Yudono, B., Gulo, F. & Strunk, J., 1 Apr 2019, In : Catalysts. 9, 4, 16 p., 323.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
Titanium dioxide
Surface plasmon resonance
Impregnation
anatase
4 Citations (Scopus)
1 Downloads (Pure)

Characterization of a nitrogen gliding arc plasmatron using optical emission spectroscopy and high-speed camera

Gröger, S., Ramakers, M., Hamme, M., Medrano, J. A., Bibinov, N., Gallucci, F., Bogaerts, A. & Awakowicz, P., 6 Feb 2019, In : Journal of Physics D: Applied Physics. 52, 6, 12 p., 065201.

Research output: Contribution to journalArticleAcademicpeer-review

plasmatrons
gliding
Optical emission spectroscopy
high speed cameras
High speed cameras
1 Citation (Scopus)
12 Downloads (Pure)

Co-aromatization of furan and methanol over ZSM-5 : a pathway to bio-aromatics

Uslamin, E., Kosinov, N., Filonenko, G. A., Mezari, B., Pidko, E. A. & Hensen, E., 6 Sep 2019, In : ACS Catalysis. 9, 9, p. 8547-8554 8 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Aromatization
Methanol
Zeolites
Catalysts
Catalyst selectivity
1 Citation (Scopus)

Color-tunable Eu 3+ and Tb 3+ Co-doped nanophosphors synthesis by plasma-assisted method

Lin, L. L., Ma, X. T., Starostin, S. A., Li, S. R., Hessel, V., Shen, J., Shang, S. M. & Xu, H. J., 15 Apr 2019, In : ChemistrySelect. 4, 14, p. 4278-4286 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Color
Plasmas
Rare earths
Terbium
Ions
5 Citations (Scopus)
24 Downloads (Pure)

Continuous, monodisperse silver nanoparticles synthesis using microdroplets as a reactor

Wojnicki, M., Tokarski, T., Hessel, V., Fitzner, K. & Luty-Błocho, M., 15 Mar 2019, In : Journal of Flow Chemistry. 9, 1, p. 1-7 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Silver
Nanoparticles
Batch reactors
Particle size analysis
Mass transfer
23 Citations (Scopus)
113 Downloads (Pure)

CO oxidation by Pd supported on CeO2(100) and CeO2(111) facets

Spezzati, G., Benavidez, A. D., DeLaRiva, A. T., Su, Y., Hofmann, J. P., Asahina, S., Olivier, E. J., Neethling, J. H., Miller, J. T., Datye, A. K. & Hensen, E. J. M., Apr 2019, In : Applied Catalysis. B, Environmental. 243, p. 36-46 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
oxidation
Oxidation
Cerium compounds
Density functional theory
3 Citations (Scopus)
44 Downloads (Pure)

Correlations between Density-Based Bond Orders and Orbital-Based Bond Energies for Chemical Bonding Analysis

Rohling, R. Y., Tranca, I. C., Hensen, E. J. M. & Pidko, E. A., 7 Feb 2019, In : Journal of Physical Chemistry C. 123, 5, p. 2843-2854 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Chemical bonds
Electronic structure
chemical bonds
orbitals
Crystals

Cost analysis of oil cake-to-biodiesel production in packed-bed micro-flow reactors with immobilized lipases

Budžaki, S., Sundaram, S., Tišma, M. & Hessel, V., Jul 2019, In : Journal of Bioscience and Bioengineering. 128, 1, p. 98-102 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

Biofuels
Lipases
Packed beds
Biodiesel
Lipase
33 Downloads (Pure)

Coverage effects in CO dissociation on metallic cobalt nanoparticles

Zijlstra, B., Broos, R., Chen, W., Oosterbeek, H., Filot, I. & Hensen, E., 2 Aug 2019, In : ACS Catalysis. 9, 8, p. 7365-7372 8 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
Cobalt
Nanoparticles
Carbon
Density functional theory
5 Citations (Scopus)
71 Downloads (Pure)

Degradation mechanisms of C6/LiNi0.5Mn0.3Co0.2O2 Li-ion batteries unraveled by non-destructive and post-mortem methods

Li, D., Li, H., Danilov, D. L., Gao, L., Chen, X., Zhang, Z., Zhou, J., Eichel, R. A., Yang, Y. & Notten, P. H. L., 15 Mar 2019, In : Journal of Power Sources. 416, p. 163-174 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
electric batteries
Cathodes
cathodes
degradation
Degradation
3 Citations (Scopus)

De novo design of organic photocatalysts: bithiophene derivatives for the visible-light induced C−H functionalization of heteroarenes

Bottecchia, C., Martín, R., Abdiaj, I., Crovini, E., Alcazar, J., Orduna, J., Blesa, M. J., Carrillo, J. R., Prieto, P. & Noël, T., 5 Mar 2019, In : Advanced Synthesis & Catalysis. 361, 5, p. 945-950 6 p.

Research output: Contribution to journalArticleAcademicpeer-review

Photocatalysts
Derivatives
Catalysts
Discrete Fourier transforms
Absorption spectra
12 Citations (Scopus)

Determination of the total vapor pressure of hydrophobic deep eutectic solvents: experiments and perturbed-chain statistical associating fluid theory modeling

Dietz, C. H. J. T., Creemers, J. T., Meuleman, M. A., Held, C., Sadowski, G., Van Sint Annaland, M., Gallucci, F. & Kroon, M. C., 18 Feb 2019, In : ACS Sustainable Chemistry & Engineering. 7, 4, p. 4047-4057 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Vapor pressure
vapor pressure
Eutectics
Fluids
fluid