Total Research Program Chemical and Process Technology

Research Output 1966 2020

2020
1 Citation (Scopus)
4 Downloads (Pure)

A quantum-chemical study of the CO dissociation mechanism on low-index Miller planes of ϴ-Fe 3 C

Broos, R. J. P., Klumpers, B., Zijlstra, B., Filot, I. A. W. & Hensen, E. J. M., 15 Feb 2020, In : Catalysis Today. 342, p. 152-160 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
Chemical activation
Carbides
Fischer-Tropsch synthesis
Cobalt

Aromatization of ethylene over zeolite-based catalysts

Uslamin, E. A., Saito, H., Kosinov, N. A., Pidko, E. A., Sekine, Y. & Hensen, E. J. M., 2020, (Accepted/In press) In : Catalysis Science & Technology.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Aromatization
Zeolites
Ethylene
Catalysts
Aromatic compounds

CFD analysis of a luminescent solar concentrator-based photomicroreactor (LSC-PM) with feedforward control applied to the synthesis of chemicals under fluctuating light intensity

de Oliveira, G. X., Lira, J. O. B., Cambié, D., Noël, T., Riella, H. G., Padoin, N. & Soares, C., 1 Jan 2020, In : Chemical Engineering Research and Design. 153, p. 626-634 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Solar concentrators
Feedforward control
Dynamic analysis
Computational fluid dynamics
Dynamic models
5 Downloads (Pure)

Computational modelling of the Fischer-Tropsch reaction on iron carbides

Broos, R. J. P., 12 Feb 2020, (Accepted/In press) Eindhoven: Technische Universiteit Eindhoven. 187 p.

Research output: ThesisPhd Thesis 1 (Research TU/e / Graduation TU/e)

Open Access
File

Deployment of membrane for propylene recovery

Gonzalez-Gonzalez de Castro, G., 2020, (In preparation) Eindhoven: Technische Universiteit Eindhoven.

Research output: ThesisPd Eng Thesis

4 Downloads (Pure)

Effect of proximity and support material on deactivation of bifunctional catalysts for the conversion of synthesis gas to olefins and aromatics

Weber, J. L., Krans, N. A., Hofmann, J. P., Hensen, E. J. M., Zecevic, J., de Jongh, P. E. & de Jong, K. P., 15 Feb 2020, In : Catalysis Today. 342, p. 161-166 6 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Synthesis gas
Alkenes
Catalyst supports
Olefins
Catalysts

Electrochemical stability of RuO2(110)/Ru(0001) model electrodes in the oxygen and chlorine evolution reactions

Goryachev, A., Etzi Coller Pascuzzi, M., Carlà, F., Weber, T., Over, H., Hensen, E. J. M. & Hofmann, J. P., 2020, (Accepted/In press) In : Electrochimica Acta.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
1 Citation (Scopus)
1 Downloads (Pure)

First-principles based microkinetic modeling of transient kinetics of CO hydrogenation on cobalt catalysts

Zijlstra, B., Broos, R., Chen, W., Filot, I. & Hensen, E., 15 Feb 2020, In : Catalysis Today. 342, p. 131-141 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Carbon Monoxide
Cobalt
Hydrogenation
Catalysts
Kinetics

First-principles microkinetics simulations of electrochemical reduction of CO2 over Cu catalysts

Zijlstra, B., Zhang, X., Liu, J-X., Filot, I. A. W., Zhou, Z., Sun, S. & Hensen, E. J. M., 2020, (Accepted/In press) In : Electrochimica Acta.

Research output: Contribution to journalArticleAcademicpeer-review

Improving the physicochemical properties of Y zeolite for catalytic cracking of heavy oil via sequential steam-alkali-acid treatments

Aghaei, E., Karimzadeh, R., Godini, H. R., Gurlo, A. & Gorke, O., 1 Mar 2020, In : Microporous and Mesoporous Materials. 294, 15 p., 109854.

Research output: Contribution to journalArticleAcademicpeer-review

Zeolites
Catalytic cracking
Steam
Alkalies
steam

Increased Activity in the Oxygen Evolution Reaction by Fe4+-Induced Hole States in Perovskite La1-xSrxFeO3

Shen, Z., Zhuang, Y., Li, W., Huang, X., Oropeza, F. E., Hensen, E. J. M., Hofmann, J. P., Cui, M., Tadich, A., Qi, D., Cheng, J., Li, J. & Zhang, K. H. L., 2020, In : Journal of Materials Chemistry A.

Research output: Contribution to journalArticleAcademicpeer-review

In situ shell-isolated nanoparticle-enhanced raman spectroscopy of nickel-catalyzed hydrogenation reactions’

Wondergem, C. S., Kromwijk, J. J. G., Slagter, M. M., Vrijburg, W. L., Hensen, E. J. M., Monai, M., Vogt, C. & Weckhuysen, B. M., 2020, (Accepted/In press) In : ChemPhysChem.

Research output: Contribution to journalArticleAcademicpeer-review

Investigation of the active phase in K-promoted MoS2 catalysts for methanethiol synthesis

Yu, M., Kosinov, N. A., van Haandel, L., Kooyman, P. J. & Hensen, E. J. M., 2020, In : ACS Catalysis.

Research output: Contribution to journalArticleAcademicpeer-review

Carbon Monoxide
Catalysts
X ray photoelectron spectroscopy
Productivity
Transmission electron microscopy

Mechanistic role of protonated polar additives in ethanol for selective transformation of biomass-related compounds

Guo, H., Duereh, A., Su, Y-Q., Hensen, E. J. M., Qi, X. & Smith Jr., R. L., 5 May 2020, In : Applied Catalysis. B, Environmental. 264, 9 p., 118509.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
ethanol
Biomass
Ethanol
Dimethyl Sulfoxide
Dehydration
29 Downloads (Pure)

Microkinetic modeling of Fischer-Tropsch synthesis on cobalt

Zijlstra, B., 15 Jan 2020, Eindhoven: Technische Universiteit Eindhoven. 243 p.

Research output: ThesisPhd Thesis 1 (Research TU/e / Graduation TU/e)

Open Access
File
14 Downloads (Pure)

Mn promotion of rutile TiO2-RuO2 anodes for water oxidation in acidic media

Etzi Coller Pascuzzi, M., Goryachev, A., Hofmann, J. P. & Hensen, E. J. M., 1 Feb 2020, In : Applied Catalysis. B, Environmental. 261, 11 p., 118225.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
rutile
Anodes
oxidation
Oxidation
Water

Porous nitrogen-doped carbon/carbon nanocomposite electrodes enable sodium ion capacitors with high capacity and rate capability

Yan, R., Leus, K., Hofmann, J. P., Antonietti, M. & Oschatz, M., Jan 2020, In : Nano Energy. 67, 8 p., 104240.

Research output: Contribution to journalArticleAcademicpeer-review

Energy storage
Nanocomposites
Capacitors
Nitrogen
Carbon

Reforming towards renewable hydrogen: biogas steam reforming in a fluidized bed membrane reactor

de Nooijer, N. C. A., 20 Feb 2020, (Accepted/In press) Eindhoven: Technische Universiteit Eindhoven.

Research output: ThesisPhd Thesis 1 (Research TU/e / Graduation TU/e)

Screening of functional solvent system for automatic aldehyde and ketone separation in aldol reaction: a combined COSMO-RS and experimental approach

Zhang, C., Song, Z., Jin, C., Nijhuis, J., Zhou, T., Noël, T., Gröger, H., Sundmacher, K., van Hest, J. & Hessel, V., 1 Apr 2020, In : Chemical Engineering Journal. 385, 10 p., 123399.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
ketone
aldehyde
Ketones
Aldehydes
Screening

Selective hydrogenation of 5 hydroxymethylfurfural and its acetal with 1,3-propanediol to 2,5-bis(hydroxymethyl)furan using supported rhenium-promoted nickel catalysts in water

Wiesfeld, J. J., Kim, M., Nakajima, K. & Hensen, E. J. M., 13 Jan 2020, (Accepted/In press) In : Green Chemistry.

Research output: Contribution to journalArticleAcademicpeer-review

The butoxylation of dodecylamine: reaction mechanism and kinetics

Müller, P., Krösschell, R. D. E., Winkenwerder, W. & van der Schaaf, J., 15 Feb 2020, In : Chemical Engineering Journal. 382, 9 p., 122939.

Research output: Contribution to journalArticleAcademicpeer-review

Amines
kinetics
Kinetics
Hydroxyl Radical
Ethylene Oxide
2019
6 Citations (Scopus)
1 Downloads (Pure)
Signal filtering and prediction
Furaldehyde
Furfural
Eutectics
Sugars
4 Citations (Scopus)
109 Downloads (Pure)

3D printed versus spherical adsorbents for gas sweetening

Middelkoop, V., Coenen, K., Schalck, J., van Sint Annaland, M. & Gallucci, F., 1 Feb 2019, In : Chemical Engineering Journal. 357, p. 309-319 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Adsorbents
Gases
adsorption
Adsorption
gas

A 14-GHz 8-bit direct digital synthesizer in InP DHBT technology

Li, X., Zhang, Y., Wang, Z., Zhang, Y., Zhang, M., Cheng, W. & Gao, H., Aug 2019, 2019 IEEE International Symposium on Radio-Frequency Integration Technology (RFIT). Piscataway: Institute of Electrical and Electronics Engineers, 3 p. 8929198

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

Bipolar transistors
ROM
Transistors
Electric power utilization
Bandwidth
21 Downloads (Pure)
Open Access
File
Phase transitions
Direct numerical simulation
Bubbles (in fluids)
Gravitation
Temperature distribution
8 Downloads (Pure)

Activation of co–mo–S hydrodesulfurization catalysts under refinery conditions: a combined SAXS/XAS study

van Haandel, L., Longo, A., Bras, W., Hensen, E. J. M. & Weber, T., 18 Oct 2019, In : ChemCatChem. 11, 20, p. 5013-5017 5 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Hydrodesulfurization
Chemical activation
activation
catalysts
Catalysts
1 Citation (Scopus)

Activity modelling of the solid-liquid equilibrium of deep eutectic solvents

Kollau, L. J. B. M., Vis, M., van den Bruinhorst, A., de With, G. & Tuinier, R., 1 Aug 2019, In : Pure and Applied Chemistry. 91, 8, p. 1341–1349 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Eutectics
Liquids
Melting point
Binary mixtures
Activity coefficients
3 Citations (Scopus)

Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels

Birdja, Y. Y., Pérez-Gallent, E., Figueiredo, M. C., Göttle, A. J., Calle-Vallejo, F. & Koper, M. T. M., 1 Sep 2019, In : Nature Energy. 4, 9, p. 732-745 14 p.

Research output: Contribution to journalReview articleAcademicpeer-review

Carbon Dioxide
Carbon dioxide
Chemical activation
pH effects
Catalyst selectivity
1 Citation (Scopus)
15 Downloads (Pure)

A facile direct route to N-(un)substituted lactams by cycloamination of oxocarboxylic acids without external hydrogen

Li, H., Wu, H., Zhang, H., Su, Y., Song, Y. & Hensen, E., 22 Aug 2019, In : ChemSusChem. 12, 16, p. 3778-3784 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Lactams
Hydrogen
hydrogen
formic acid
Acids
36 Downloads (Pure)

A method for obtaining a stable lignin: polar organic solvent composition via mild solvolytic modifications

Kouris, P., Hensen, E., Boot, M. & Oevering, H., 21 Mar 2019, Patent No. WO2019053287, Priority date 18 Sep 2017

Research output: PatentPatent publication

Open Access
File
Lignin
Organic solvents
Feedstocks
Chemical analysis
Patents and inventions

A multi-perspectives analysis of methane oxidative coupling process based on miniplant-scale experimental data

Godini, H. R., Azadi, M., Penteado, A., Khadivi, M., Wozny, G. & Repke, J. U., 1 Nov 2019, In : Chemical Engineering Research and Design. 151, p. 56-69 14 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methane
Ethylene
Economics
Natural gas conditioning
Ethane
26 Downloads (Pure)

An asymmetric organocatalytic aldol reaction of a hydrophobic aldehyde in aqueous medium running in flow mode

Schober, L., Ratnam, S., Yamashita, Y., Adebar, N., Pieper, M., Berkessel, A., Hessel, V. & Gröger, H., Mar 2019, In : Synthesis. 51, 5, p. 1178-1184 7 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Enantioselectivity
Propanol
Aldehydes
2-Propanol
Substrates

An Fe stabilized metallic phase of NiS2 for the highly efficient oxygen evolution reaction

Ding, X., Li, W., Kuang, H., Qu, M., Cui, M., Zhao, C., Qi, D. C., Oropeza, F. E. & Zhang, K. H. L., 28 Dec 2019, In : Nanoscale. 11, 48, p. 23217-23225 9 p.

Research output: Contribution to journalArticleAcademicpeer-review

Oxygen
Catalysts
Doping (additives)
Reactive Oxygen Species
Hydroxides

An improved kinetic model for micromixing characterization using the Villermaux-Dushman method

Manzano Martinez, A., Haase, S., Assirelli, M. & van der Schaaf, J., 12 Nov 2019, Proceeding: 2019 AIChE Annual Meeting. p. 1 1 p.

Research output: Chapter in Book/Report/Conference proceedingConference contributionAcademicpeer-review

Open Access
Kinetics
Climate change
Industry
Profitability
Engineers
1 Citation (Scopus)
11 Downloads (Pure)

Application of metal oxide semiconductors in light-driven organic transformations

Riente Paiva, P. & Noël, T., 22 Aug 2019, In : Catalysis Science & Technology. 9, 19, p. 5186-5232 47 p.

Research output: Contribution to journalReview articleAcademicpeer-review

Open Access
File
Metals
Photocatalysts
Chemical stability
Transition metals
Energy efficiency
358 Downloads (Pure)

A quantum chemical study of environmental catalysis at the metal-ceria interface

Su, Y., 16 Jan 2019, Eindhoven: Technische Universiteit Eindhoven. 180 p.

Research output: ThesisPhd Thesis 1 (Research TU/e / Graduation TU/e)

Open Access
File
Catalytic converters
Cerium compounds
Precious metals
Catalysis
Metals
12 Downloads (Pure)
Open Access
File
Cyclohexanols
Gold
Gases
Nanoparticles
Oxidation
16 Citations (Scopus)
71 Downloads (Pure)

A search for natural hydrophobic deep eutectic solvents based on natural components

van Osch, D. J. G. P., Dietz, C. H. J. T., van Spronsen, J., Kroon, M. C., Gallucci, F., van Sint Annaland, M. & Tuinier, R., 4 Feb 2019, In : ACS Sustainable Chemistry & Engineering. 7, 3, p. 2933-2942 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Eutectics
Thymol
Menthol
Riboflavin
Water
3 Citations (Scopus)
4 Downloads (Pure)

A site-sensitive quasi-in situ strategy to characterize Mo/HZSM-5 during activation

Vollmer, I., Kosinov, N., Szécsényi, Á., Li, G., Yarulina, I., Abou-Hamad, E., Gurinov, A., Ould-Chikh, S., Aguilar-Tapia, A., Hazemann, J. L., Pidko, E., Hensen, E., Kapteijn, F. & Gascon, J., 1 Feb 2019, In : Journal of Catalysis. 370, p. 321-331 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methane
Carbon Monoxide
Benzene
Zeolites
Chemical activation

Assessment of the location of Pt nanoparticles in Pt/zeolite Y/γ‑Al2O3 composite catalysts

Oenema, J., Hofmann, J. P., Hensen, E., Zecevic, J. & de Jong, K. P., 2 Oct 2019, (Accepted/In press) In : ChemCatChem.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Zeolites
Nanoparticles
catalysts
nanoparticles
Catalysts

A theoretical study of the reverse water-gas shift reaction on Ni(111) and Ni(311) surfaces

Zhang, M., Zijlstra, B., Filot, I., Li, F., Wang, H., Li, J. & Hensen, E., 2019, (Accepted/In press) In : Canadian Journal of Chemical Engineering.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
Water gas shift
Carbon Monoxide
Chemical activation
Water
Redox reactions
2 Downloads (Pure)

A versatile mono-quaternary ammonium salt as a mesoporogen for the synthesis of hierarchical zeolites

Bolshakov, A., van Hoof, A., Mezari, B., Kosinov, N. & Hensen, E., 7 Dec 2019, In : Catalysis Science & Technology. 9, 23, p. 6737-6748 12 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Zeolites
Ammonium Compounds
Salts
Butenes
1-Butanol
41 Downloads (Pure)

Bio-based chemicals: Selective aerobic oxidation of tetrahydrofuran-2,5-dimethanol to tetrahydrofuran-2,5-dicarboxylic acid using hydrotalcite-supported gold catalysts

Yuan, Q., Hiemstra, K., Meinds, T. G., Chaabane, I., Tang, Z., Rohrbach, L., Vrijburg, W., Verhoeven, T., Hensen, E. J. M., van der Veer, S., Pescarmona, P. P., Heeres, H. J. & Deuss, P. J., 4 Mar 2019, In : ACS Sustainable Chemistry & Engineering. 7, 5, p. 4647-4656 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
hydrotalcite
Dicarboxylic Acids
Gold
gold
catalyst

Biomass gasification syngas cleaning system design

Perez Salmeron, C., 22 Oct 2019, Eindhoven: Technische Universiteit Eindhoven.

Research output: ThesisPd Eng Thesis

1 Citation (Scopus)

Boosting CO2 methanation activity on Ru/TiO2 catalysts by exposing (001) facets of anatase TiO2

Chai, S., Men, Y., Wang, J., Liu, S., Song, Q., An, W. & Kolb, G., 1 Oct 2019, In : Journal of CO2 Utilization. 33, p. 242-252 11 p.

Research output: Contribution to journalArticleAcademicpeer-review

Methanation
anatase
physicochemical property
Titanium dioxide
catalyst
8 Downloads (Pure)

Catalytic conversion of biomass to biophenol

Hensen, E., Huang, X. & Ouyang, X., 19 Sep 2019, IPC No. PCT/NL2019/050151, Patent No. WO2019177458, 19 Sep 2019, Priority No. NL20182020595 20180315

Research output: PatentPatent publication

Open Access
File
Patents and inventions
Biomass
Lignin
Phenol
Dealkylation
1 Citation (Scopus)
7 Downloads (Pure)

Catalytic conversion of lignin in woody biomass into phenolic monomers in methanol/water mixtures without external hydrogen

Ouyang, X., Huang, X., Zhu, J., Boot, M. & Hensen, E., 19 Aug 2019, In : ACS Sustainable Chemistry & Engineering. 7, 16, p. 13764-13773 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Lignin
lignin
Methanol
methanol
Hydrogen
3 Citations (Scopus)
57 Downloads (Pure)

Cellulose conversion to ethylene glycol by tungsten oxide-based catalysts

Wiesfeld, J., Peršolja, P., Rollier, F. A., Elemans - Mehring, A. & Hensen, E., 1 Aug 2019, In : Molecular Catalysis. 473, 110400.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
tungsten oxides
Ethylene Glycol
Ethylene glycol
cellulose
Cellulose
1 Citation (Scopus)
9 Downloads (Pure)

Ceria-Zirconia encapsulated Ni nanoparticles for CO2 methanation

Vrijburg, W., van Helden, J. W. A., Parastaev, A., Groeneveld, E., Pidko, E. & Hensen, E., 12 Aug 2019, In : Catalysis Science & Technology. 9, 18, p. 5001-5010 10 p.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Methanation
Cerium compounds
Zirconia
Nanoparticles
Catalysts
1 Citation (Scopus)
15 Downloads (Pure)

Characterization and effect of Ag(0) vs. Ag(I) species and their localized plasmon resonance on photochemically inactive TiO 2

Handoko, C. T., Moustakas, N. G., Peppel, T., Springer, A., Oropeza, F. E., Huda, A., Bustan, M. D., Yudono, B., Gulo, F. & Strunk, J., 1 Apr 2019, In : Catalysts. 9, 4, 16 p., 323.

Research output: Contribution to journalArticleAcademicpeer-review

Open Access
File
Carbon Monoxide
Titanium dioxide
Surface plasmon resonance
Impregnation
anatase